Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (5): 865-875.DOI: 10.6023/cjoc201310007 Previous Articles     Next Articles

Reviews

二茂钛杂环化合物的合成及应用研究进展

王萍, 章彦婧, 王伟, 郑卫新   

  1. 杭州师范大学材料与化学化工学院 杭州 310036
  • 收稿日期:2013-10-10 修回日期:2013-12-30 出版日期:2014-05-25 发布日期:2014-01-10
  • 通讯作者: 郑卫新 E-mail:wxzheng@hznu.edu.cn
  • 基金资助:

    国家自然科学基金(No. 20972037)、浙江省重点科技创新团队建设项目(No. 2010R50017)、杭州师范大学优秀中青年教师支持计划(No. HNUEYT 2011-01-013)、教育部创新团队“长江学者和创新团队发展计划资助(No. IRT 1231)资助项目.

Progresses on Synthesis and Applications of Bis(cyclopentadieny)titanacycles

Wang Ping, Zhang Yanjing, Wang Wei, Zheng Weixin   

  1. College of Material, Chemistry & Chemical Engineering, Hangzhou Normal University, Hangzhou 310036
  • Received:2013-10-10 Revised:2013-12-30 Online:2014-05-25 Published:2014-01-10
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 20972037), the Special Funds for Key Innovation Team of Zhejiang Province (No. 2010R50017), the Excellent Young Teacher Support Program of Hangzhou Normal University (No. 2011-01-013) and the Program for Changjiang Scholars and Innovative Research Team in Chinese University (No. IRT 1231).

Titanacycles, containing two carbon metal bonds in the molecule, have emerged as a series of significant intermediates in organic synthesis. The structural characteristics, preparation and synthetic applications of bis(cyclopentadienyl)titana-three, four, five, or six-membered rings have been summarized in the present review, in which the selective cleavage and reactivity of C—Ti bond in the titanacyle have been discussed.

Key words: titana-three-menbered ring, titana-four-menbered ring, titana-five-menbered ring, titana-six-menbered ring, preparation, selective reaction