Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (1): 1-14.DOI: 10.6023/cjoc201409019 Previous Articles     Next Articles



刘强a,b, 田兵a,b, 田平b, 童晓峰a, 林国强b   

  1. a 华东理工大学上海市功能性材料化学重点实验室 上海 200237;
    b 中国科学院上海有机化学研究所天然产物有机合成化学重点实验室 上海 200032
  • 收稿日期:2014-09-09 修回日期:2014-09-30 发布日期:2014-10-09
  • 通讯作者: 田平, 童晓峰, 林国强;;
  • 基金资助:

    国家自然科学基金(Nos. 21372243, 21102161)资助项目.

Recent Progress on Cu-Catalyzed Asymmetric Conjugate Borylation to α,β-Unsaturated Compounds

Liu Qianga,b, Tian Binga,b, Tian Pingb, Tong Xiaofenga, Lin Guo-Qiangb   

  1. a Shanghai Key Laboratory of Functional Materials Chemistry, East China University of Science and Technology, Shanghai 200237;
    b CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
  • Received:2014-09-09 Revised:2014-09-30 Published:2014-10-09
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21372243, 21102161).

Organoborons are an important class of organic compounds, because organoboronic acids and their derivatives can be readily converted into a wide variety of functionalities in a stereospecific manner. Cu-catalyzed asymmetric conjugate borylation of unsaturated compounds with bis(pinacolato)diboron (B2pin2) has emerged as a novel synthetic tool to afford a variety of organoboron compounds. Herein, this research progress, which involves using bisphosphine, N-heterocyclic carbine, and other chiral ligands, is summarized.

Key words: copper, α,β-unsaturated compounds, asymmetric conjugate borylation