Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (2): 258-273.DOI: 10.6023/cjoc201509030 Previous Articles     Next Articles

Reviews

过渡金属催化烯丙醇异构化反应的研究进展

钟业辛a, 任凯b, 谢小敏b, 张兆国a,b   

  1. a 上海应用技术学院化学与环境工程学院 上海 201418;
    b 上海交通大学化学化工学院 上海 200240
  • 收稿日期:2015-09-24 修回日期:2015-10-23 出版日期:2016-02-25 发布日期:2015-11-03
  • 通讯作者: 任凯, 张兆国 E-mail:kairenhb@sjtu.edu.cn;zhaoguo@sjtu.edu.cn
  • 基金资助:

    国家自然科学基金(No. 21472124)资助项目

Transition Metal Catalyzed Isomerization Reaction of Allylic Alcohols

Zhong Yexina, Ren Kaib, Xie Xiaominb, Zhang Zhaoguoa,b   

  1. a School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418;
    b School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240
  • Received:2015-09-24 Revised:2015-10-23 Online:2016-02-25 Published:2015-11-03
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21472124).

Carbonyl compounds are key synthetic intermediates in the fields of medicine, pesticide, perfumes and cosmetics. In recent years, transition metal catalyzed isomerization of allylic alcohols to synthesize various carbonyl compounds has drawn much attention and been explored extensively, due to their high atomic economy and unique superiority. The recent development of the isomerization reactions of allylic alcohols catalyzed by various transition metals is summarized.

Key words: allylic alcohols, transition metal, isomerization reaction, carbonyl compounds, asymmetric isomerization reaction , tandem reaction