Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (9): 2442-2448.DOI: 10.6023/cjoc201702035 Previous Articles     Next Articles



常毅, 刘梦阳, 牛梦园   

  1. 河南师范大学化学化工学院 新乡 453007
  • 收稿日期:2017-02-25 修回日期:2017-04-12 发布日期:2017-05-02
  • 通讯作者: 常毅
  • 基金资助:


Efficient Synthesis of Anionic and Cationic Water-Soluble Porphyrins

Chang Yi, Liu Mengyang, Niu Mengyuan   

  1. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007
  • Received:2017-02-25 Revised:2017-04-12 Published:2017-05-02
  • Contact: 10.6023/cjoc201702035
  • Supported by:

    Project supported by the Key Program for High School of Henan Province (No. 16A150012) and the Science Foundation for Young Scholar of Henan Normal University (No. 214QK15) and the Doctoral Science Research Foundation of Henan Normal University (No. qd15113).

A kind of cationic water-soluble porphyrin containing pyridinium group and a kind of anionic water-soluble porphyrin containing sulfonic group were synthesized efficiently according to the chosen conditions. During the synthesis process, 5,10,15,20-tetra(pyridin-4-yl)porphyrin and 5,10,15,20-tetra-phenol porphyrin were chosen as the precursors, while triethylene glycol monomethyl ether and manganese were introduced on porphyrin as the functional group. These procedures have the advantages of operation simplicity, high yields, mild conditions, and provide a good method for the synthesis of similar types of water soluble porphyrins at the same time.

Key words: water-soluble, porphyrins, manganese porphyrin, substituents, synthesis, modification