Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (5): 1181-1188.DOI: 10.6023/cjoc201703003 Previous Articles     Next Articles

Special Issue: 热点论文合辑

ARTICLE

碳龙配合物的烯基化研究

路正宇a, 陈江溪b, 夏海平a   

  1. a 厦门大学化学化工学院 厦门 361005;
    b 厦门大学材料学院 厦门 361005
  • 收稿日期:2017-03-01 修回日期:2017-03-17 发布日期:2017-04-10
  • 通讯作者: 夏海平 E-mail:hpxia@xmu.edu.cn
  • 基金资助:

    国家自然科学基金(Nos.21490573,21332002,21472156)资助项目.

Synthesis of Olefinic Carbolong Complexes

Lu Zhengyua, Chen Jiangxib, Xia Haipinga   

  1. a College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005;
    b College of Material, Xiamen University, Xiamen 361005
  • Received:2017-03-01 Revised:2017-03-17 Published:2017-04-10
  • Contact: 10.6023/cjoc201703003 E-mail:hpxia@xmu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21490573, 21332002, 21472156).

Carbolong complexes are a new type of metalla-aromatic compounds with novel skeleton and interesting properties, which could be used as potential interesting materials. However, most of them do not have reactive organic functional groups, which hinder their applications as functional materials via chemical modifications. Olefinic group is a reactive functional group that can be used for polymerization or click reaction and so on. In this work, the synthesis of carbolong complexes attached an olefinic group, which could be used to prepare carbolong-containing materials, is reported based on their reactivity.

Key words: carbolong, metallapentalyne, metallapentalene, olefinic, osmium