Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (11): 2841-2849.DOI: 10.6023/cjoc201706005 Previous Articles     Next Articles



朱文明, 应炜炜, 魏文廷   

  1. 宁波大学材料科学与化学工程学院 宁波 315211
  • 收稿日期:2017-06-04 修回日期:2017-07-02 发布日期:2017-07-14
  • 通讯作者: 魏文廷
  • 基金资助:


Progress in Carbon-Oxygen Bonds Formation Using tert-Butyl Hydroperoxide

Zhu Wenming, Ying Weiwei, Wei Wenting   

  1. School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211
  • Received:2017-06-04 Revised:2017-07-02 Published:2017-07-14
  • Contact: 10.6023/cjoc201706005
  • Supported by:

    Project supported by the Research Funds of Ningbo University (No. ZX2016000706), the Foundation of Ningbo University (No. XYL17009) and the K. C. Wong Magna Fund in Ningbo University.

The formation of carbon-oxygen bonds is one of the hot topics in the field of organic synthesis methodology. Recently, the remarkable progress has been made in construction of carbon-oxygen bonds using tert-butyl hydroperoxide in radical reactions. The present protocol, which utilizes tert-butyl hydroperoxide as oxidant and oxygen source, provides a green and atom economy approach to ketones, esters and alcohols etc. This review will summarize the recent development in this area on the basis of different chemical bonds.

Key words: tert-butyl hydroperoxide, carbon-oxygen bond, radical reaction