Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (8): 2060-2066.DOI: 10.6023/cjoc201712043 Previous Articles     Next Articles

Special Issue: 有机超分子化学合辑



王恒a,b, 张宇坤a,b, 邹胜a, 曹金鑫a, 黄晴菲a, 王启卫a, 朱槿a   

  1. a 中国科学院成都有机化学研究所 成都 610041;
    b 中国科学院大学 北京 100049
  • 收稿日期:2017-12-29 修回日期:2018-02-14 发布日期:2018-03-16
  • 通讯作者: 黄晴菲, 朱槿;
  • 基金资助:


Design and Synthesis of a Class of Aromatic Polyamide Foldamer

Wang Henga,b, Zhang Yukuna,b, Zou Shenga, Cao Jinxina, Huang Qingfeia, Wang Qiweia, Zhu Jina   

  1. a Chengdu Institute of Organic Chemistry, Chinese Academy of Science, Chengdu 610041;
    b Universtiy of Chinese Academy of Sciense, Beijing 100049
  • Received:2017-12-29 Revised:2018-02-14 Published:2018-03-16
  • Contact: 10.6023/cjoc201712043;
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 20772123).

Long aromatic polymer chains which based on 3,5-diaminobenzoic acid derivatives and 4,6-dihydroxyisophthalic acid derivatives are designed and synthesized. The results of solubility, NMR, UV-Vis spectrum and circular dichroism (CD) experments indicate that the polymer adopts a hollow helical conformation that is stablized by intramolecular H-bonding interaction between side chains.

Key words: aromatic polyamide, foldamer, helice