Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (6): 1292-1318.DOI: 10.6023/cjoc201801003 Previous Articles     Next Articles

Reviews

“受阻路易斯酸碱对”活化小分子反应研究进展

张震北a,b, 孙伟b, 曹治珊c   

  1. a 河南科技学院化学化工学院 新乡 453003;
    b 中国科学院兰州化学物理研究所 羰基合成与选择氧化国家重点实验室 兰州 730000;
    c 河南科技学院动物科技学院 新乡 453003
  • 收稿日期:2018-01-03 修回日期:2018-02-26 出版日期:2018-06-25 发布日期:2018-03-08
  • 通讯作者: 张震北,E-mail:zhenbei.zhang@hist.edu.cn E-mail:zhenbei.zhang@hist.edu.cn
  • 基金资助:

    国家自然科学基金(No.21473226)资助项目.

Progress in Activation of Small Molecules Promoted by Frustrated Lewis Pairs

Zhang Zhenbeia,b, Sun Weib, Cao Zhishanc   

  1. a College of Chemistry & Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003;
    b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;
    c College of Animal Science and Veterinary Medicine, Henan Institute of Science and Technology, Xinxiang 453003
  • Received:2018-01-03 Revised:2018-02-26 Online:2018-06-25 Published:2018-03-08
  • Contact: 10.6023/cjoc201801003 E-mail:zhenbei.zhang@hist.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21473226).

Frustrated Lewis pairs (FLPs) chemistry has grown rapidly during the last decade and provided a new strategy for the activation of a variety of small molecules, such as hydrogen, olefins, alkynes, carbon dioxide, tetrahydrofuran and hydrosilane etc. The activations of these molecules have probided a new method in the utility of main group element. The structure and reactivity of FLPs are reviewed and the recent progress in activation of small molecules promoted by frustrated Lewis pairs is introduced.

Key words: frustrated Lewis pairs, B (C6F5)3, metal-free catalysis, organic synthesis