Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (3): 811-820.DOI: 10.6023/cjoc201807011 Previous Articles     Next Articles

Articles

锰氮掺杂的碳材料催化苄基醚氧化生成酯

刘晶a, 万聪a, 郑爱丽a, 王连月b, 殷凯越a, 刘丹丹a, 王圣德a, 任兰会a, 高爽b   

  1. a 潍坊医学院药学院 潍坊 261053;
    b 中国科学院大连化学物理研究所 大连 116023
  • 收稿日期:2018-07-05 修回日期:2018-09-04 出版日期:2019-03-25 发布日期:2018-10-20
  • 通讯作者: 任兰会, 高爽 E-mail:Ren_lanhui@163.com;sgao@dicp.ac.cn
  • 基金资助:

    国家自然科学基金(Nos.21773227,21773232)资助项目.

α-Oxygenation of Benzylic Ethers to Esters Using MnOx-N@C Catalyst

Liu Jinga, Wan Conga, Zheng Ailia, Wang Lianyueb, Yin Kaiyuea, Liu Dandana, Wang Shengdea, Ren Lanhuia, Gao Shuangb   

  1. a College of Pharmacy, Weifang Medical University, Weifang 261053;
    b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023
  • Received:2018-07-05 Revised:2018-09-04 Online:2019-03-25 Published:2018-10-20
  • Contact: 10.6023/cjoc201807011 E-mail:Ren_lanhui@163.com;sgao@dicp.ac.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21773227, 21773232).

A catalytic system for the oxidation of benzylic ethers to esters has been developed utilizing reusable MnOx-N@C as catalyst and tert-butyl hydroperoxide (TBHP) as benign oxidant under neat condition. The catalytic oxidation system has good functional groups tolerance and excellent chemoselectivity, and this catalytic procedure can also be scaled up.

Key words: C-H bonds, oxidation, ether, ester, solvent-free