Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (5): 1284-1292.DOI: 10.6023/cjoc201809012 Previous Articles     Next Articles

Reviews

环糊精参与的过渡金属催化有机反应

陈雅琪, 桂鑫, 段尊斌, 朱丽君, 项玉芝, 夏道宏   

  1. 中国石油大学(华东)化学工程学院 重质油国家重点实验室 青岛 266580
  • 收稿日期:2018-09-06 修回日期:2018-12-03 出版日期:2019-05-25 发布日期:2019-01-18
  • 通讯作者: 夏道宏 E-mail:xiadh@upc.edu.cn
  • 基金资助:

    国家自然科学基金(No.21376265)资助项目.

Transition Metal Catalyzed Organic Reaction Involving Cyclodextrin

Chen Yaqi, Gui Xin, Duan Zunbin, Zhu Lijun, Xiang Yuzhi, Xia Daohong   

  1. State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum(East China), Qingdao 266580
  • Received:2018-09-06 Revised:2018-12-03 Online:2019-05-25 Published:2019-01-18
  • Contact: 10.6023/cjoc201809012 E-mail:xiadh@upc.edu.cn
  • Supported by:

    Project supported by the the National Natural Science Foundation of China (No. 21376265).

Cyclodextrin is a kind of cyclic oligosaccharide which is composed of the D-pyran glucose units connected with the α-1,4-glycosidic bond. Cyclodextrin has the rigidly tapered cavity of hydrophobic inner and hydrophilic outer. Cyclodextrin has been attracted more and more attention from scientists since it was discovered, owning to its special space cavity of hydrophilic inner and hydrophilic outer. As an important industrial catalyst, transition metal catalyst can combine with the cyclodextrin system to simultaneously exert the catalytic properties of the metal and the molecular recognition and phase transfer of cyclodextrin, which greatly improves its catalytic performance. In this paper, the transition metal catalyzed organic reactions involving cyclodextrin are reviewed, and these reactions are described in terms of the metal valence from 0 to 4. Finally, the development and foreground of these co-catalyst systems involving metal and cyclodextrin are prospected. It is expected that the catalytic system will have a wider application in the future, and a more efficient and selective catalytic system will be continuously developed.

Key words: cyclodextrin, transition metal, catalysis, reaction, synthesis, complexes