Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (9): 2443-2457.DOI: 10.6023/cjoc201901028 Previous Articles     Next Articles

REVIEW

亚砜脱氧还原方法研究进展

李伟林, 陈炫颖, 郑天骄, 邹祺, 陈文博   

  1. 上海电力大学 上海市电力材料防护与新材料重点实验室 上海 200090
  • 收稿日期:2019-01-18 修回日期:2019-03-30 出版日期:2019-09-25 发布日期:2019-04-16
  • 通讯作者: 邹祺, 陈文博 E-mail:qzou@shiep.edu.cn;wenbochen@shiep.edu.cn
  • 基金资助:

    上海市自然科学基金(No.17ZR1447100)和上海市科学技术委员会(No.14DZ2261000)资助项目.

Research Progress on Reduction of Sulfoxides to Thiothers

Li Weilin, Chen Xuanying, Zheng Tianjiao, Zou Qi, Chen Wenbo   

  1. Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, Shanghai University of Electric Power, Shanghai 200090
  • Received:2019-01-18 Revised:2019-03-30 Online:2019-09-25 Published:2019-04-16
  • Contact: 10.6023/cjoc201901028 E-mail:qzou@shiep.edu.cn;wenbochen@shiep.edu.cn
  • Supported by:

    Project supported by the Natural Science Foundation of Shanghai City (No. 17ZR1447100) and the Science and Technology Commission of Shanghai Munic-ipality (No. 14DZ2261000).

As one of the most important transformations in organic synthesis, deoxygenation reduction of sulfoxides to thioethers has attracted wide attention in researches and applications. With the development of organicmetallic chemistry, many mild and practical methods have been developed to reduce sulfoxides. In this review, based on the types of the reducing agents, the research progress on the deoxygenation reduction of sulfoxides to thiothers in recent 20 years is summarized. In addition, the advantages and disadvantages of these reduction systems, some reaction mechanisms and the prospects of research in this field are discussed.

Key words: sulfoxide, deoxygenation reduction, thioether, research progress