Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (2): 364-375.DOI: 10.6023/cjoc201908009 Previous Articles     Next Articles


刘金宝a, 李鹏a,b, 姚子健a,b   

  1. a 上海城建职业学院 上海 201415;
    b 上海应用技术大学化学与环境工程学院 上海 201418
  • 收稿日期:2019-08-05 修回日期:2019-09-17 发布日期:2019-10-09
  • 通讯作者: 刘金宝, 姚子健;
  • 基金资助:

Recent Progress of Discrete Metallacycles Based on the Half-Sandwich Ir/Rh/Ru Motifs

Liu Jinbaoa, Li Penga,b, Yao Zijiana,b   

  1. a Department of Science and Technology, Shanghai Urban Construction Vocational College, Shanghai 201415;
    b School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418
  • Received:2019-08-05 Revised:2019-09-17 Published:2019-10-09
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21601125), the Chenguang Scholar of Shanghai Municipal Education Commission (Nos. 16CG64, 18CGB12).

Discrete metallacycle complexes have attracted considerable attention because of their widely used in host-guest chemistry, gas adsorption, molecular recognition and catalysis. Thus exploring new framework complexes, studying their physical and chemical properties and applications have become one of the most active and exciting areas of inorganic chemistry, organic chemistry and supramolecular chemistry. Half-sandwich organometallic units based on ruthenium, iridium and rhodium are often utilized to prepare diverse metallacylce complexes due to the following advantages:the solubility of these metal complexes can be enhanced, the hemisphere of the metal center is perfectly shielded, minimizing the complexity of reactions, and the products with different structures are easily synthesized. In this paper, the synthesis and application of discrete type metal framework complexes with half-sandwich structures of ruthenium, iridium and rhodium are reviewed.

Key words: organometallic, half-sandwich, Ir/Rh/Ru, metallacycle