Recent Progresses in the Epoxidation of Olefins UsingHydrogen Peroxide as Oxidant

Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (03): 358-367. Previous Articles Next Articles

Review

以双氧水为氧源的烯烃环氧化反应

欧阳小月^a，江焕峰*^,b

(^a中国科学技术大学化学系合肥 230026)
(^b华南理工大学化学科学学院广州 510640)

收稿日期:2006-01-26 修回日期:2006-05-23 出版日期:2007-02-13 发布日期:2007-02-13
通讯作者: 江焕峰

Recent Progresses in the Epoxidation of Olefins UsingHydrogen Peroxide as Oxidant

OUYANG Xiao-Yue^a,JIANG Huan-Feng*^,b

(^aDepartment of Chemistry, University of Science and Technology of China, Hefei 230026)
(^bCollege of Chemistry, South China University of Technology, Guangzhou 510640)

Received:2006-01-26 Revised:2006-05-23 Online:2007-02-13 Published:2007-02-13

Contact: JIANG Huan-Feng

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Abstract

Based on the reaction medium and the elements in the catalysts, the recent progresses of epoxidation of alkenes with hydrogen peroxide have been reviewed.

Key words: hydrogen peroxide, catalysis, epoxidation, olefin

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OUYANG Xiao-Yue^a,JIANG Huan-Feng*^,b. Recent Progresses in the Epoxidation of Olefins UsingHydrogen Peroxide as Oxidant[J]. Chin. J. Org. Chem., 2007, 27(03): 358-367.

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[1]	Zhao Yating, Zeng Junjie, Xia Wujiong. Visible-Light-Induced α-C(sp³)—H Amination Reactions of Tertiary Amines [J]. Chinese Journal of Organic Chemistry, 2020, 40(1): 133-139.
[2]	Sun Guijiu, Xiao Fanhua, Duan Weiliang. Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to Quinone Monoketals [J]. Chinese Journal of Organic Chemistry, 2020, 40(1): 61-68.
[3]	Zhang Xiaopeng, Zhu Yanjie, Zhu Yisong, Li Zhengwei, Zhang Guisheng. Advances in Synthesis of 2,3-Dihydroquinazolin-4(1H)-ones [J]. Chin. J. Org. Chem., 2019, 39(9): 2392-2402.
[4]	Xie Zongbo, Li Hongxia, Liu Liansheng, Lan Jin, Hu Zhiyu, Le Zhanggao. Synthesis of Quinazolinone Derivatives Catalyzed by Alkaline Protease [J]. Chin. J. Org. Chem., 2019, 39(9): 2632-2638.
[5]	Wang Qiaotian, Han Caifang, Feng Xiangqing, Du Haifeng. Chiral Spiro Dienes Derived Boranes for Asymmetric Hydrosilylation of Ketones [J]. Chin. J. Org. Chem., 2019, 39(8): 2257-2263.
[6]	Gu Yingchun, Huang You. Tributylphosphine Catalyzed Cross Rauhut-Currier Reaction of Chalcones and Acrylates [J]. Chin. J. Org. Chem., 2019, 39(8): 2251-2256.
[7]	Shi Chonghui, Xiao Benxian, Du Wei, Chen Yingchun. Phosphine-Catalyzed Formal[6+2] Cycloadditions of α'-Methylene 2-Cyclopentenones [J]. Chin. J. Org. Chem., 2019, 39(8): 2218-2225.
[8]	Lan Tianlei, Zhang Yue, Liu Wei, Xi Chanjuan, Chen Chao. Carbazolation Study of Active Arenes with Carbazole-Containing Hypervalent Iodine(III) Reagents [J]. Chinese Journal of Organic Chemistry, 2019, 39(8): 2166-2174.
[9]	Xiao Yuanyuan, Wang Youming, Zhou Zhenghong. Asymmetric Synthesis of Novel Fused Polycyclic 3,4-Dihydro-pyrano[4,3-b]pyran-5(2H)-ones via an Organocatalyzed Formal[3+3] Annulation [J]. Chin. J. Org. Chem., 2019, 39(8): 2203-2210.
[10]	Wei Liang, Xiao Lu, Hu Yuanzheng, Wang Zuofei, Tao Haiyan, Wang Chunjiang. Recent Advances in Metallated Azomethine Ylides for the Synthesis of Chiral Unnatural α-Amino Acids [J]. Chin. J. Org. Chem., 2019, 39(8): 2119-2130.
[11]	Huang Hongtai, Li Tao, Wang Jiazhuang, Qin Guiping, Xiao Tiebo. Recent Advance in Transition-Metal-Catalyzed Silylation of C-H Bonds [J]. Chin. J. Org. Chem., 2019, 39(6): 1511-1521.
[12]	Chen Xiaoling, Chen Jingwen, Bao Zongbi, Yang Qiwei, Yang Yiwen, Ren Qilong, Zhang Zhiguo. MIL-101(Cr)-SO₃H Catalyzed Transfer Hydrogenation of 2-Substituted Quinoline Derivatives [J]. Chin. J. Org. Chem., 2019, 39(6): 1681-1687.
[13]	Shan He, Ling Li, Hu Jianfeng, Zhang Hao. Application in the Asymmetric Catalytic Reactions of Chiral Cyclopentadienyl-Transition-Metal Complexes [J]. Chin. J. Org. Chem., 2019, 39(6): 1548-1556.
[14]	Wang Ligeng, Yu Qin, Feng Chun, Zhang Yan, Hu Jun. Efficient Synthesis of Dibromoalkanes and Iodoacetates from Olefins Using ZnAl-XO₃^--LDHs/LiX (X=Br, I) as Halogen Sources [J]. Chin. J. Org. Chem., 2019, 39(6): 1787-1793.
[15]	Cheng Dongdong, Zhang Yunxiao, Wang Jinming, Bai Suping. Copper(I) in situ-Catalyzed Azide-Alkyne Cycloaddition in the Synthesis of Long Chain Bifunctional Molecules:Preparation of Biotin Conjugated Glaucocalyxin A Analogs [J]. Chin. J. Org. Chem., 2019, 39(6): 1794-1801.