Recent Progresses in the Epoxidation of Olefins UsingHydrogen Peroxide as Oxidant

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Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (03): 358-367. Previous Articles Next Articles

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以双氧水为氧源的烯烃环氧化反应

欧阳小月^a，江焕峰*^,b

(^a中国科学技术大学化学系合肥 230026)
(^b华南理工大学化学科学学院广州 510640)

收稿日期:2006-01-26 修回日期:2006-05-23 发布日期:2007-02-13
通讯作者: 江焕峰

Recent Progresses in the Epoxidation of Olefins UsingHydrogen Peroxide as Oxidant

OUYANG Xiao-Yue^a,JIANG Huan-Feng*^,b

(^aDepartment of Chemistry, University of Science and Technology of China, Hefei 230026)
(^bCollege of Chemistry, South China University of Technology, Guangzhou 510640)

Received:2006-01-26 Revised:2006-05-23 Published:2007-02-13

Contact: JIANG Huan-Feng

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Abstract

Based on the reaction medium and the elements in the catalysts, the recent progresses of epoxidation of alkenes with hydrogen peroxide have been reviewed.

Key words: hydrogen peroxide, catalysis, epoxidation, olefin

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OUYANG Xiao-Yue^a,JIANG Huan-Feng*^,b. Recent Progresses in the Epoxidation of Olefins UsingHydrogen Peroxide as Oxidant[J]. Chin. J. Org. Chem., 2007, 27(03): 358-367.

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[1]	Lin Cong, Gao Zhenbo, Teng Qiuxun, Xue Bowen, Li Xiaohua, Gao Fei, Shen Liang. Synthesis of Vinyl-Substituted Dihydroisoquinolone via Ru(II)-Catalyzed C—H Functionalization/Annulation of Imidates [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2863-2870.
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[3]	Yuan Kangning, Zhao Yuying, Chang Honghong, Tian Jun, Gao Wenchao. Recent Advances in AlCl₃-Promoted Organic Reactions [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2607-2625.
[4]	Wang Su, Zhang Youlu, Ba Yanyan, Zhang Jingyu, Sun Demei. Study and Applications of Stereoselective Olefin Metathesis Reactions [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2725-2741.
[5]	Liu Yingjie, Meng Jianping, Li Chen, Lin Liqing, Xu Ying. Progress in the Synthesis of Isoxazoline Derivatives by Cycloylation of Allyl Oxime [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2742-2754.
[6]	Yang Min, Xia Lili, Zhou Xiaoqin, Jia Chengli, Ji Min, Wang Peng. A Ratiometric Fluorescent Probe for Imaging Hydrogen Peroxide in Living Cells [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2888-2894.
[7]	Liu Jiahao, Han Jingjie, Yi Xiaoyi, Liu Chao, He Piao. Research Progress of Homogeneous Catalyst for the Dehydrogenation of Formic Acid [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2658-2668.
[8]	Ma Xiantao, Yu Jing, Wang Zilong, Zhang Yun, Zhou Qiuju. Efficient Activation of Allylic Alcohols in Pd-Catalyzed Allylic Substitution Reactions [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2669-2677.
[9]	Zheng Kanghe, Zhou Bingwei, Jin Hongwei, Liu Yunkui. Bifunctional Phosphine Ligand-Enabled Gold(I)-Catalyzed Efficient Synthesis of 1,5-Benzodiazepines [J]. Chinese Journal of Organic Chemistry, 2020, 40(8): 2520-2525.
[10]	Chen Ying, Jing Xiaobi, Yu Lei. Polyaniline-Supported Copper-Catalyzed Buchwald-Hartwig Couplings of Pyrimidin-2-amines [J]. Chinese Journal of Organic Chemistry, 2020, 40(8): 2570-2574.
[11]	Zhang Yahui, Liu Yang, Miao Jiankang, Hao Wenyan. Copper-Catalyzed Cascade Bicyclization of o-Alkenylphenyl Isothiocyanates with Sodium Azide Leading to the 5H-Benzo[d]tetrazolo[5,1-b] [1,3]thiazines [J]. Chinese Journal of Organic Chemistry, 2020, 40(8): 2426-2432.
[12]	Sun Kai, Liu Haidong, Xie Qi, Luo Haiqing. Progress in the Synthesis of Arylphosphonates via Ar-P Bond Construction [J]. Chinese Journal of Organic Chemistry, 2020, 40(8): 2275-2289.
[13]	Lin Mei, Wu Fan, Liu Tianhui, Chen Zhitao, Xu Xiuzhi, Ke Fang. Visible-Light Promoted Preparation of Benzimidazoles by Eosin Y Catalyzed Reaction of Benzonitrile Derivatives in Water [J]. Chinese Journal of Organic Chemistry, 2020, 40(8): 2563-2569.
[14]	Wu Lizuo, Zhang Fengyuan, Zhang Zhentao, Shang Lei, Liu Yu. Ming-Phos/Copper(I)-Catalyzed Asymmetric Intermolecular[3+2] Cycloaddition of Azomethine Ylides with Trifluoromethyl Enones [J]. Chinese Journal of Organic Chemistry, 2020, 40(8): 2460-2467.
[15]	Sun Mingli, Zhang Jiajun, Zhang Yicheng, Li Pinhua, Wang Lei. A Silver-Catalyzed Functionalization of 1-Bromoalkynes: Highly Regio-and Stereo-selective Synthesis of (Z)-β-Bromo-1-arylvinyl Aryl Esters [J]. Chinese Journal of Organic Chemistry, 2020, 40(8): 2419-2425.