Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (11): 1424-1427. Previous Articles     Next Articles




  1. (α洛阳师范学院化学系 洛阳 471022)
    (b河南师范大学化学与环境科学学院 新乡 453002)
  • 收稿日期:2007-05-28 修回日期:2007-04-27 发布日期:2007-10-20
  • 通讯作者: 渠桂荣

Synthesis and Electrochemistry of Novel Tetrathiafulvalene- calixarene Derivatives

ZHAO Bang-Tun*,α,CHEN Jun-Qingb,QU Gui-Rong*,b   

  1. (α Department of Chemistry, Luoyang Normal University, Luoyang 471022)
    (b College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453002)
  • Received:2007-05-28 Revised:2007-04-27 Published:2007-10-20
  • Contact: QU Gui-Rong

The calix[4]arene-thione 2a and 2b were prepared by the reaction of dibromo-calix[4]arene 1a and 1b with di(tetraethylammonium) bis(1,3-dithiol-2-thione-4,5-dithiolate) zincate in refluxing with high diluted acetonitrile, respectively. Then, two new tetrathiafulvalene-calix[4]arenes 3a and 3b were obtained by the cross-coupling of 2a and 2b with 4,5-biscynaoethylthio-1,3-dithiole-2-one mediated by triethylphosphite, respectively. All new compounds were characterized by 1H NMR, 13C NMR, IR, MS spectra and elemental analysis. Meanwhile, preliminary electrochemical behaviours of 3a and 3b were reported along with the X-ray structure of calixarene-thione 2b.

Key words: calixarene, synthesis, X-ray structure, electrochemistry, tetrathiafulvalene