Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (09): 1611-1615. Previous Articles     Next Articles

Reports

2-取代-4,5-双(α-呋喃基)噁唑的合成及发光性能的研究

孙继奎a ; 张 峰a ; 李亚卓a ; 高大维*,a ;
张玉敏a ; 赵天琦a; 陈晓东b
  

  1. (a吉林大学化学学院 长春 130012)
    (b吉林大学测试科学实验中心 长春 130023)
  • 收稿日期:2006-10-30 修回日期:2007-12-29 发布日期:2008-09-20
  • 通讯作者: 高大维

Synthesis of 2-Substituted-4,5-di(α-furyl)oxazole and Their Luminescent Property

SUN, Ji-Kuia ; ZHANG, Fenga ; LI, Ya-Zhuoa ; GAO, Da-Wei*,a ;ZHANG, Yu-Mina; ZHAO, Tian-Qia; CHEN, Xiao-Dongb
  

  1. (a College of Chemistry, Jilin University, Changchun 130012)
    (b Experimental Center of Testing Science, Jilin University, Changchun 130023)
  • Received:2006-10-30 Revised:2007-12-29 Published:2008-09-20
  • Contact: GAO, Da-Wei

Furoin was synthesized with furfural as raw material in the presence of Vitamin B1 (VB1) as a catalyst. The monoesters of furoin were synthesized by esterification of corresponding the acyl chloride with the furoin. The new 2-substituted-4,5-di(α-furyl)oxazoles were obtained via treatment of the monoesters with ammo-nium acetate and acetic acid, characterized with elemental analysis, IR, 1H NMR, mass spectra, and their luminescence property was simply studied with UV and fluorescence spectra.

Key words: furoin, 2-substituted-4,5-di(α-furyl)oxazole, luminescent property, esterification, synthesis, monoester of furoin