Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (10): 1735-1739. Previous Articles     Next Articles

Original Articles


吕恩年; 徐 琰* ; 冉春玲 ; 刘红海; 乔纯杰; 樊耀亭*; 朱 玉

  1. (郑州大学化学系 郑州 450052)
  • 收稿日期:2008-01-23 修回日期:2008-03-17 发布日期:2008-10-20
  • 通讯作者: 徐 琰* ; 樊耀亭*

Synthesis and Characterization of Novel Ferrocenyl α-Aminophosphonic Esters

LÜ, En-Nian; XU, Yan*; RAN, Chun-Ling; LIU, Hong-Hai ;
QIAO, Chun-Jie ; FAN, Yao-Ting* ; ZHU, Yu

  1. (Department of Chemistry, Zhengzhou University, Zhengzhou 450052)

  • Received:2008-01-23 Revised:2008-03-17 Published:2008-10-20
  • Contact: XU, Yan*; FAN, Yao-Ting*

A series of α-aminophosphonates bearing the ferrocenyl moiety were obtained by the addition of diethyl phosphite to an azomethine bond of Schiff bases. The compounds were characterized by elemental analysis, IR, 1H NMR and 31P NMR spectra. X-ray crystallography of 3h reveals that it belongs to triclinic system P-1 space group, with a=0.9728 nm, b=1.1056 nm, c=1.3713 nm, α=108.445(2)°, β=98.649(2)°, γ=104.890(2)°, final R=0.049, wR=0.1152.

Key words: α-aminophosphonate, ferrocene, synthesis, crystal structure, chiral