|
|
Chinese Journal of Organic Chemistry 2006, 26(08) 1125-1129 DOI:
ISSN: 0253-2786 CN: 31-1321/O6 |
|
|
|
|
Current Issue |
Archive |
Search
[Print]
[Close]
|
|
| Reports |
|
|
Synthesis and Characterization of Caged Bicyclic Phosphorous Quadridentate Silicon Complex |
|
|
ZHANG Li-Li,LIU An-Hua*,ZENG Xing-Rong,WEN Yong-Xiang |
|
|
(College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640) |
|
|
Abstract：
A novel caged bicyclic phosphorous quadridentate silicon complex was synthesized by reaction of 1-oxo-1-phospha-4-chloromethyl-2,6,7-trioxabicyclo[2.2.2]octane with the pentacoordinate silicon complex, which was synthesized directly from SiO2 by non-carbothermal reduction. Structure of the synthesized substance was confirmed by FTIR, MS, 13C and 29Si MAS NMR spectra, while thermal analysis tests indicated that the target compound possessed exceptional thermal stability. |
|
Keywords：
silica
caged bicyclic phosphorous quadridentate silicon complex
synthesis, charaterization
|
|
|
Received 2005-10-24 Revised 2006-02-23 Online: |
|
|
DOI: |
|
|
Fund: |
|
Corresponding Authors: LIU An-Hua |
|
Email: |
|
|
About author: |
|
|
| References： |
|
| Similar articles |
| 1．Liao, Yong ; Huang, Wenhai ; Hu, Chunqi; Hu, Yongzhou; Sheng, Rong*.Dehydrogenation Synthesis of 1,3-Diphenylpyrazoles [J]. Chinese Journal of Organic Chemistry, 2009,29(05): 784-787 |
| 2．Yang Jinfei .Stydy of Synthesis of Trimethylphenyl Phosphate Catalyzed by TiSiW_ (12)O_(40)/TiO_2[J]. Chinese Journal of Organic Chemistry, 2003,23(11): 1317-1319 |
| 3．Yang Shuijin;Liang Yongguang;Sun Jutang .Preparation and Catalytic Activity of TiSiW_(12)O_(40j)/TiO_2 in Synthesis of Butyric Esters[J]. Chinese Journal of Organic Chemistry, 2003,23(11): 1294-1298 |
| 4．Wang Lei;Li Pinhua;Chen Yuncai;Yan Jincan;Wang Min .A Convenient and Rapid Microwave-Enhanced, Solventless Desilylation Procedure Using Potassium Carbonate Doped on Silica Gel[J]. Chinese Journal of Organic Chemistry, 2003,23(7): 720-723 |
| 5．Zheng Ailian;Wu Yuanliu .The oxidation of 1-bromo-3-tolyloxy-2-propanol with Jones reagent[J]. Chinese Journal of Organic Chemistry, 1993,13(6): 616-618 |
| 6．Hao Aiyou;Huang Huiqin;Lin Jimao;Ma Chen .Convenient preparation of α-tert-butylated ketones and aldehydes by zinc chloride/microporous spherical silica gel column chromatography[J]. Chinese Journal of Organic Chemistry, 1999,19(4): 435-437 |
| 7．WU ZHENZHONG;JIN XIAOLI;GUO HUIJU;HUANG GUOHUA;XU YUANYAO .Synthesis of 4'-N-alkyl(aryl) aminomethyl benzo-18-crown-6 and polymer-and silica-supported crown ethers [J]. Chinese Journal of Organic Chemistry, 1983,3(2): 110-114 |
| 8．LONG HAIYAN;YUAN CHENGYE .Studies on organophosphorus compounds xiii. separation of acidic phosphates and phosphonates by silica-loaded paper chromatography [J]. Chinese Journal of Organic Chemistry, 1985,5(4): 322-325 |
| 9．ZHOU WEISHAN;WU RINAN;WANG ZHIMIN .The catalytic epoxidation of allylic alcohols in the presence of calcium hydride and silica gel [J]. Chinese Journal of Organic Chemistry, 1988,8(6): 539-542 |
| 10．XIA PENG;ZHANG ZHIGANG;YUAN SHENGYAO .The selective hydrolysis of 3-methoxy-estra-2,5(10)-diene-11β-ol with an oxalic acid reagent supported on silica gel [J]. Chinese Journal of Organic Chemistry, 1989,9(5): 448-450 |
| 11．WANG ZHIMIN;ZHOU WEISHAN .The effect of catalytic amount of calcium hydride and silica gel on Sharpless asymmetric epoxidation [J]. Chinese Journal of Organic Chemistry, 1992,12(1): 29-34 |
| 12．WEN Yong-Xiang,LIU An-Hua* .Study on the Synthesis of Silsesquioxane[J]. Chinese Journal of Organic Chemistry, 2005,25(04): 470-474 |
| 13．ZHANG GUISHENG;SHI QIZENG;CHEN MIFENG;CAI KUN .Preparation of silica gel-supported methylammonium chlorochromate and its use in oxidation of alcohols [J]. Chinese Journal of Organic Chemistry, 1997,17(5): 450-453 |
| 14．LI HUIZHANG;LI TONGSHUANG;YU TAO;LI JITAI;CHU HONG .Dry oxidation of benzoin under microwave irradiation [J]. Chinese Journal of Organic Chemistry, 1998,18(2): 180-182 |
| 15．LI Xiao-Qing,DU Xiao-Hua*,XU Zhen-Yuan* .Toluene Nitration Catalyzed by Metal Triflates[J]. Chinese Journal of Organic Chemistry, 2006,26(08): 1111-1114 |
|
| Copyright by Chinese Journal of Organic Chemistry |
