Synthesis of lanthanocene amides and their applications  as single- component initiators in polymerization of polar  monomers

Abstract

This article describes our research results in recent years on the synthesis, molecular structure of lanthanocene amides and their applications in the polymerization of polar monomers, including methyl methacrylate, (dimethylamino) ethyl methacrylate, and phenyl isocyanate and ring-opening polymerization of ε-caprolactone, as well. The relationship between the structures of lanthanocene amides and catalytic activities was discussed, and the polymerization mechanism was suggested.

Key words: CYCLOPENTADIENYL GROUP, AMINATION, RARE EARTH METAL COMPLEX, SYNTHESIS, INITIATOR, CATALYSIS, MONOMER, LIVING POLYMERIZATION

CLC Number:

O627

Cite this article

Shen Qi;Yao Yingming. Synthesis of lanthanocene amides and their applications as single- component initiators in polymerization of polar monomers[J]. Chin. J. Org. Chem., 2001, 21(11): 1018-1023.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Lin Cong, Gao Zhenbo, Teng Qiuxun, Xue Bowen, Li Xiaohua, Gao Fei, Shen Liang. Synthesis of Vinyl-Substituted Dihydroisoquinolone via Ru(II)-Catalyzed C—H Functionalization/Annulation of Imidates [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2863-2870.
[2]	Pan Chao, Liu Peng, Wu An'guo, Li Ming, Wen Lirong, Guo Weisi. Electrochemical-Promoted Synthesis of 2-Thiazolines via Selenylation/Cyclization of N-Allylthioamides [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2855-2862.
[3]	Li Fangyao, Huang Lin, Zhou Xiaoqun, Li Qian, Ma Xianli, Duan Wengui, Wang Xiu. Synthesis and Cytotoxicity Evaluation of Dehydroabietic Acid Derivatives Bearing Nitrate Moiety [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2845-2854.
[4]	Jiang Guofang, Lu Yue, Li Hongxia, Hu Zhiyu, Zhu Xiao, Xie Zongbo, Le Zhanggao. New Use of Non-natural Catalytic Activity of Pepsin: Highly Efficient Synthesis of Tetrahydroquinazolines [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2827-2835.
[5]	Liu Yingjie, Meng Jianping, Li Chen, Lin Liqing, Xu Ying. Progress in the Synthesis of Isoxazoline Derivatives by Cycloylation of Allyl Oxime [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2742-2754.
[6]	Luo Chunyan, Ma Wenjing, Lv Liang, Pang Huailin, Xiang Juncheng, Zhou Liqi, Yin Dulin, Liu Jiyong. Synthesis and Insecticidal Activity of Novel meta-Diamide Compounds Containing Cyclopropyl Group [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2963-2970.
[7]	Liang Wei, Tan Chengxia, Weng Jianquan, Liu Xinghai. Advances on Synthesis and Biological Activities of Mesoionic Compounds [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2702-2713.
[8]	Yuan Kangning, Zhao Yuying, Chang Honghong, Tian Jun, Gao Wenchao. Recent Advances in AlCl₃-Promoted Organic Reactions [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2607-2625.
[9]	Zhang Jingpeng, Yang Zhaokai, Qin Yaoguo, Yang Xinling. Design, Synthesis and Biological Activity of (E)-β-Farnesene Analogues Containing 1,2,3-Thiadiazole [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2971-2979.
[10]	Zhang Luye, Zhang Yang, Wang Zhengjie, Wang Tao, Li Erdong, Liu Limin, Liu Xiujuan, Zheng Jiaxin, Ke Yu, Shan Lihong, Liu Hongmin, Zhang Qiurong. Synthesis and Antitumor Activity of Novel Quinazoline Derivatives Containing Acrylamide [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2804-2810.
[11]	Lei Kang, Li Pan, Zhou Xiaoyun, Wang Shiben, Wang Xuekun, Ji Lusha, Liu Renmin, Xu Xiaohua. Design, Synthesis and Herbicidal Activity of 5-Acylbarbituric Acid Derivatives and Study of Molecular Mode of Action [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2788-2797.
[12]	Liu Jiahao, Han Jingjie, Yi Xiaoyi, Liu Chao, He Piao. Research Progress of Homogeneous Catalyst for the Dehydrogenation of Formic Acid [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2658-2668.
[13]	Kong Yaolei, Sun Xiaotong, Weng Jianquan. Selectfluor as “Fluorine-Free” Functional Reagent Applied to Organic Synthesis under Transition Metal-Free Conditions [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2641-2657.
[14]	Zhang Zhu, Li Jiazhu, Wang Xinyue, Ma Jihua, Wang Xu, Wang Jinjun. Nitration (Nitroalkylation) of Pheophorbide and Synthesis of Chlorophyllous Chlorin Derivatives [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2895-2903.
[15]	Ma Xiantao, Yu Jing, Wang Zilong, Zhang Yun, Zhou Qiuju. Efficient Activation of Allylic Alcohols in Pd-Catalyzed Allylic Substitution Reactions [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2669-2677.

茂基稀土胺化物的合成及其作为单组份引发剂引发极性单体聚合的研究