Chin. J. Org. Chem. ›› 2012, Vol. ›› Issue (03): 574-579.DOI: 10.6023/cjoc1109062 Previous Articles     Next Articles

Articles

带官能团的双有机碘化锌试剂与酰氯的反应研究

徐长明, 杨磊, 黄丹凤, 牛腾, 胡雨来, 王克虎   

  1. 西北师范大学化学化工学院 兰州 730070
  • 收稿日期:2011-09-06 修回日期:2011-10-27 出版日期:2012-03-25 发布日期:2012-03-24
  • 通讯作者: 黄丹凤 E-mail:huangdf@nwnu.edu.cn; huyl@nwnu.edu.cn
  • 基金资助:

    国家自然科学基金(No. 20472068)、甘肃省自然科学基金(No. 3ZS041-A25-003)、教育部高等学校博士学科点专项科研基金(No. 200807360001)资助项目.

Study on the Coupling Reaction of Fuctionalized Bisorganozinc Iodides and Acyl Chlorides

Xu Changming, Yang Lei, Huang Danfeng, Niu Teng, Hu Yulai, Wang Kehu   

  1. College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070
  • Received:2011-09-06 Revised:2011-10-27 Online:2012-03-25 Published:2012-03-24
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 2072068), the Natural Science Foundation of Gansu Province (No. 3ZS041-A25-003), and the Specialized Research Fund of the Doctoral Propram of Higher Education (No. 200807360001).

This paper investigated the preparation of fuctionalized bisorganozinc iodides with ether, ester, carbonyl groups and the reactions with acyl chlorides in the presence of CuCN?2LiCl generating fuctionalized diketones. The method has the advantages of mild and simple reaction conditions with medium yields, and provides a simple synthesis procedure of fuctionalized long-chain diketone compounds.

Key words: bisorganozinc iodide, acyl chloride, diketone compound