Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (1): 26-35.DOI: 10.6023/cjoc201308038 Previous Articles     Next Articles



姚家斌, 徐梦瑜, 严志强, 伍晚花, 杨成   

  1. 四川大学化学学院 成都 610064
  • 收稿日期:2013-08-29 修回日期:2013-10-14 发布日期:2013-10-31
  • 通讯作者: 杨成
  • 基金资助:

    国家自然科学基金(Nos. 21372165,23321061)资助项目.

Supramolecular Photochirogenesis with Cyclodextrins

Yao Jiabin, Xu Mengyu, Yan Zhiqiang, Wu Wanhua, Yang Cheng   

  1. College of Chemistry, Sichuan University, Chengdu 610064
  • Received:2013-08-29 Revised:2013-10-14 Published:2013-10-31
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21372165, 23321061).

In the present paper, supramolecular chiral photoreactions using cyclodextrins (CDs) as chiral inductors, including monomolecular photochirogenic reactions, bimolecular photochirogenic reactions, photochemical catalysis as well as the wavelength effects in photochirogenesis, have been summarized. This review focused on the binding behavior of CDs with different photosubstrates, the characteristics of chiral photoreactions mediated by CDs, the products distribution and stereoselectivity of chiral photoreactions with CDs and their working mechanisms. This paper concluded the advantages of CDs as host molecules used for chiral photoreactions, the problems existing in these supramolecular photochirogenesis systems and the perspective in this multidisciplinary research field.

Key words: cyclodextrins, supramolecular chemistry, stereochemistry, photochemistry, photocatalysis