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Chinese Journal of Chemistry 2009, 27(12) 2423-2425 DOI:
ISSN: 1001-604X CN: 31-1547/O6 |
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Copper(I) Oxide Catalyzed Formation of C—S Bond Mediated by N,N-Type Ligand |
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FENG Yisi 1,2; ZHAO Xiaoyang1; WANG Jueyu1; ZHENG Fayin1; XU Huajian*,1,2 |
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a School of Chemical Engineering, Hefei University of Technology, Hefei, Anhui 230009
b Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engineering, Hefei, Anhui 230009 |
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Abstract：
1,10-Phenanthroline, a simple and cheap N,N-type ligand, was found to work well as the ligand of C—S coupling catalyzed by Cu2O. The corresponding coupling products were synthesized in good to excellent yields (75%—99%) in DMSO at 80 ℃. A variety of aryl halides and thiols were investigated and satisfactory results were obtained. |
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Keywords：
1,10-phenanthroline
C—S coupling
Cu catalyzed
Cu2O
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Received 2009-04-21 Revised 2009-07-09 Online: 2009-08-14 |
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DOI: |
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Fund: |
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Corresponding Authors: XU Hua-Jian |
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Email: hjxu@mail.ustc.edu.cn |
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