Electrochemical Impedance Spectroscopic Study of Electrodeposited Bi2Te3-based Thin Films

doi:10.6023/A1110103

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (10): 1173-1178.DOI: 10.6023/A1110103 Previous Articles Next Articles

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电沉积Bi₂Te₃ 基薄膜的电化学阻抗谱研究

林青含^a, 邱丽琴^a, 程璇^a,b, 周健^a

a 厦门大学材料学院材料科学与工程系厦门 361005;
b 福建省特种先进材料重点实验室厦门 361005

投稿日期:2011-10-10 修回日期:2012-03-07 发布日期:2012-05-28
通讯作者: 程璇, 周健 E-mail:xcheng@xmu.edu.cn
基金资助:
福建省特种先进材料重点实验室基金(No. 2006L2003).

Electrochemical Impedance Spectroscopic Study of Electrodeposited Bi₂Te₃-based Thin Films

Lin Qinghan^a, Qiu Liqin^a, Cheng Xuan^a,b, Zhou Jian^a

a Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005;
b Fujian Key Laboratory of Advanced Materials, Xiamen University, Xiamen 361005

Received:2011-10-10 Revised:2012-03-07 Published:2012-05-28
Supported by:
Project supported by the Fujian Key Laboratory of Advanced Materials, China (No. 2006L2003).

The Bi₂Te₃-based thin films have been prepared by electrochemical deposition on stainless-steel substrates. The microstructure and composition of the films were studied by X-ray diffraction (XRD) and electron probe microanalysis (EPMA). The deposition mechanisms of Bi₂Te₃ thin films on stainless-steel substrates were preliminary investigated using electrochemical impedance spectroscopy (EIS). The results showed that the similar deposition mechanisms were obtained for Bi-Te binary and Bi-Te-Se ternary systems, i.e., the Bi³⁺, HTeO₂⁺ and H2SeO3 were electrochemically reduced to form simple substances Bi(0), Te(0) and Se(0), respectively, then the Bi₂Te₃-based compounds were formed by reacting Te(0) or Se(0) with Bi(0). For Bi-Sb-Te ternary system, the HTeO₂⁺ was first electrochemically reduced to form simple substance Te(0), and then the Bi₂Te₃-based compounds were formed by reacting Te(0) with Bi³⁺ and Sb(III). The deposition processes were controlled by electrochemical polarization.

Key words: Bi₂Te₃, electrochemical impedance spectroscopy, electrodeposition

Cite this article

Lin Qinghan, Qiu Liqin, Cheng Xuan, Zhou Jian. Electrochemical Impedance Spectroscopic Study of Electrodeposited Bi₂Te₃-based Thin Films[J]. Acta Chimica Sinica, 2012, 70(10): 1173-1178.

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电沉积Bi₂Te₃ 基薄膜的电化学阻抗谱研究

Electrochemical Impedance Spectroscopic Study of Electrodeposited Bi₂Te₃-based Thin Films

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电沉积Bi2Te3 基薄膜的电化学阻抗谱研究