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About the Cover:Li, Na & Wang, Huan et al. on page 1293-1299: Unveiling the dynamic interplay in chemical reactions, this study explores the rotational diffusion kinetics of Cu(I)-catalyzed alkyne-azide cycloaddition. The authors observe that molecular rotation decelerates while translation accelerates, suggesting a conversion of rotational to translational energy induced by molecular alignment. These findings offer a novel perspective on non-classical diffusion phenomena beyond the Stokes-Einstein relation.
Ablajan, Keyume et al. on page 1372-1378: A metal-free, visible-light-induced defluorinative acylation of α-trifluoromethyl alkenes with aromatic carboxylic anhydrides is developed. This protocol offers an efficient and operationally simple route to synthesize valuable γ,γ-difluoroallylic ketones with broad functional group tolerance. -
About the Cover:Ablajan, Keyume et al. on page 1372-1378: A metal-free, visible-light-induced defluorinative acylation of α-trifluoromethyl alkenes with aromatic carboxylic anhydrides is developed. This protocol offers an efficient and operationally simple route to synthesize valuable γ,γ-difluoroallylic ketones with broad functional group tolerance.
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