Bifunctional Ligand Promoted Pd-Catalyzed Asymmetric Allylic Etherification/Amination

doi:10.6023/A13040394

Acta Chimica Sinica ›› 2013, Vol. 71 ›› Issue (9): 1239-1242.DOI: 10.6023/A13040394 Previous Articles Next Articles

Communication

双功能配体促进的钯催化不对称醚化和胺化反应

杜乐^a,b, 曹鹏^b, 廖建^a,b

a 中国科学院成都有机化学研究所成都 610041;
b 中国科学院成都生物研究所天然产物研究中心成都610041

投稿日期:2013-04-11 发布日期:2013-04-22
通讯作者: 廖建,E-mail:jliao@cib.ac.cn E-mail:jliao@cib.ac.cn
基金资助:
项目受国家自然科学基金(Nos. 21272226, 21202160 and 21072186)资助.

Bifunctional Ligand Promoted Pd-Catalyzed Asymmetric Allylic Etherification/Amination

Du Le^a,b, Cao Peng^b, Liao Jian^a,b

a Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041;
b Natural Products Research Center, Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041

Received:2013-04-11 Published:2013-04-22
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21272226, 21202160 and 21072186).

1. Bifunctional Ligand Promoted Pd-Catalyzed Asymmetric Allylic Etherification/Amination.PDF(7231KB)

Abstract

A serious of bissulfoxide-phosphine ligands are examined on the Bronsted basicity of sulfinyl moiety. The effect of secondary binding property of the ligand is demostrated in Pd-catalyzed asymmetric allylic etherification and amination (up to 99% ee). And the application scope of this methodology to hydrogen-donor nucleophiles is investigated.

Key words: chiral bissulfoxide-phosphine ligands, bifunctional, hydrogen bond, Pd-catalysis, allylic etherification and amination

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Du Le, Cao Peng, Liao Jian. Bifunctional Ligand Promoted Pd-Catalyzed Asymmetric Allylic Etherification/Amination[J]. Acta Chimica Sinica, 2013, 71(9): 1239-1242.

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双功能配体促进的钯催化不对称醚化和胺化反应

Bifunctional Ligand Promoted Pd-Catalyzed Asymmetric Allylic Etherification/Amination

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