Acta Chim. Sinica ›› 2015, Vol. 73 ›› Issue (12): 1245-1249.DOI: 10.6023/A14120888 Previous Articles     Next Articles

Special Issue: 碳氢键官能团化



陆庆全, 易红, 雷爱文   

  1. 武汉大学化学与分子科学学院 武汉 430072
  • 投稿日期:2014-12-25 发布日期:2015-03-04
  • 通讯作者: 雷爱文
  • 基金资助:


Autoxidative Coupling and Its Applications to C-H Functionalization

Lu Qingquan, Yi Hong, Lei Aiwen   

  1. College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072
  • Received:2014-12-25 Published:2015-03-04
  • Supported by:

    Project supported by the 973 Program(Nos. 2012CB725302, 2011CB808600), the National Natural Science Foundation of China(Nos. 21390400, 21272180, 21302148), and the Research Fund for the Doctoral Program of Higher Education of China(No. 20120141130002) and the Program for Changjiang Scholars and Innovative Research Team in University(No. IRT1030) and the Ministry of Science and Technology of China(No. 2012YQ120060). The Program of Introducing Talents of Discipline to Universities of China(111 Program) is also appreciated.

As a highly economic and efficient strategy for chemical bond formation, oxidative coupling has been widely applied in synthetic organic chemistry. Recently, Klussmann, Jiao and Huo et al. groups have successfully achieved the direct functionalization of Csp3-H and Csp2-H bonds through developing simple, elegant autoxidative coupling reactions, which makes a significant progress in this filed. This highlight mainly reviews the recent advances in autoxidative coupling.

Key words: oxidative coupling, C-H bond functionalization, dioxygen, green chemistry, autoxidation