Acta Chim. Sinica ›› 2015, Vol. 73 ›› Issue (6): 487-497.DOI: 10.6023/A15020090 Previous Articles     Next Articles

Special Issue: 共价有机多孔聚合物



周宝龙, 陈龙   

  1. 天津大学理学院化学系 天津 300072
  • 投稿日期:2015-02-02 发布日期:2015-04-08
  • 通讯作者: 陈龙
  • 基金资助:

    项目受国家重点基础研究规划项目(No. 2015CB856500)和天津大学-海外杰出青年人才引进计划资助.

New Strategies for the Synthesis of Covalent Organic Porous Polymers

Zhou Baolong, Chen Long   

  1. Department of Chemistry, School of Science, Tianjin University, Tianjin 300072
  • Received:2015-02-02 Published:2015-04-08
  • Supported by:

    Project supported by the National Basic Research Program of China (grant No. 2015CB856500) and Tianjin University's Recruitment Program of Global Young Experts.

Covalent organic porous polymers (COPs) are a kind of novel porous polymers formed by covalent bonds linkage between organic building blocks. They feature intrinsic microporous or mesoporous structures and thus exhibit enormous potential applications in energy, chemicals absorption and separation, photovoltaics, gas storage, heterogeneous catalysis, biochemical sensing and so on. Although many reactions and various monomers are available for their synthesis and the resulted frameworks are robust, many challenges still remain. For example, COPs synthesized via traditional methods are usually amorphous and insoluble, their structures are hardly controlled and it is difficult for further processing. To address these issues, many new kinds of methods and strategies are exploited in recent years, it figures out a new direction towards future development of covalent organic porous polymers. Herein, we will give a brief introduction on some recent important progress made in such area.

Key words: covalent organic porous polymers, mechanochemistry, confined polymerization, surface polymerization