Bulk Single Crystal Growth of a Two-Dimensional Halide Perovskite Ferroelectric for Highly Polarized-Sensitive Photodetection※

doi:10.6023/A21120613

Acta Chimica Sinica ›› 2022, Vol. 80 ›› Issue (3): 237-243.DOI: 10.6023/A21120613 Previous Articles Next Articles

Special Issue: 中国科学院青年创新促进会合辑

Communication

大尺寸二维卤化物钙钛矿铁电晶体的生长及偏振光电探测性能研究^※

张芬^a^,^b, 李霄琪^b, 韩世国^b, 邬发发^b, 刘希涛^a^,^b^,^*(), 孙志华^a^,^b, 罗军华^a^,^b

a 福建师范大学化学与材料学院福州 350007
b 中国科学院福建物质结构研究所福州 350002

投稿日期:2021-12-31 发布日期:2022-02-11
通讯作者: 刘希涛
作者简介:
^※ 庆祝中国科学院青年创新促进会十年华诞.
基金资助:
国家自然科学基金(21833010); 国家自然科学基金(21921001); 国家自然科学基金(22075285); 国家自然科学基金(22125110); 中国科学院前沿科学重点研究项目(ZDBS-LY-SLH024); 福建省自然科学基金(2020J01112); 中国科学院战略性先导研究项目(XDB20010200); 中国科学院青年创新促进会(2020307); 博士后创新研究计划(BX2021315)

Bulk Single Crystal Growth of a Two-Dimensional Halide Perovskite Ferroelectric for Highly Polarized-Sensitive Photodetection^※

Fen Zhang^a^,^b, Xiaoqi Li^b, Shiguo Han^b, Fafa Wu^b, Xitao Liu^a^,^b(), Zhihua Sun^a^,^b, Junhua Luo^a^,^b

a Fujian Normal University, College of Chemistry and Materials Science, Fuzhou 350007
b Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002

Received:2021-12-31 Published:2022-02-11
Contact: Xitao Liu
About author:
^※ Dedicated to the 10th anniversary of the Youth Innovation Promotion Association, CAS.
Supported by:
National Natural Science Foundation of China(21833010); National Natural Science Foundation of China(21921001); National Natural Science Foundation of China(22075285); National Natural Science Foundation of China(22125110); Key Research Program of Frontier Sciences of the Chinese Academy of Sciences(ZDBS-LY-SLH024); Natural Science Foundation of Fujian Province(2020J01112); Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20010200); Youth Innovation Promotion of Chinese Academy of Sciences(2020307); National Postdoctoral Program for Innovative Talents(BX2021315)

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Abstract

Low-dimensional semiconductors, especially recent emerging two-dimensional halide perovskites, have shown great potential in extensive optoelectronic applications due to their large structural anisotropy, unique quantum well effect and excellent semiconductor properties. Meanwhile, the bulk photovoltaic effect with a highly sensitive angle-resolved photoresponse arising from ferroelectric materials presents a promising approach for highly polarized-sensitive photodetection. Despite the blooming development of two-dimensional halide perovskite ferroelectric materials, it is a great challenge to grow bulk single crystals of two-dimensional halide perovskite ferroelectric, which restricts their further applications in polarized-sensitive optoelectronic devices. This work mainly focuses on the developing of low-dimensional halide perovskite ferroelectric crystals with excellent photoelectric response. Two-dimensional (2D) halide perovskite ferroelectric (iPA)₂EA₂Pb₃I₁₀ (iPA=isopentammonium, EA=ethylammonium) was synthesized by a solution method through the reaction of stoichiometric lead acetate, isoamine and ethylamine in concentrated aqueous hydroiodic acid. Meanwhile, high quality centimeter-size single crystals of ferroelectric (iPA)₂EA₂Pb₃I₁₀ with the max dimensions up to 15 mm×15 mm×3 mm have been grown via temperature cooling method. On the basis of grown bulk single crystals, further investigations on the crystal structure, optical properties measurements and electrical properties characterization were carried out. The photoelectric response performance and polarization photodetection performance of photoelectric detectors based on the compound ferroelectric single crystal assembly. The result indicated that the unique two-dimensional perovskite structure endows (iPA)₂EA₂Pb₃I₁₀ with strong optical anistropy, narrow bandgap (1.80 eV) and fascinating photoelectric features (on/off ratio=10³). Strikingly, the fabricated photodetectors based on ferroelectric crystal (iPA)₂EA₂Pb₃I₁₀ manifest excellent photoelectric features, including large dichroism ratio (2.3), high responsibility (193 mA•W^–1) and photodetectivity (7.0×10¹¹ Jones), better than most photodetector based on intrinsic optical anisotropy of 2D materials. This work will be of great significance to lay a foundation for the exploring of multifunctional halide perovskites and points out the direction for bulk grown of highly anisotropic halide perovskite ferroelectric crystals and promotes their further applications in highly polarized-sensitive photodetection.

Key words: ferroelectric, crystal growth, hybrid perovskites, two-dimensional structure, polarized-sensitive photodetection

Cite this article

Fen Zhang, Xiaoqi Li, Shiguo Han, Fafa Wu, Xitao Liu, Zhihua Sun, Junhua Luo. Bulk Single Crystal Growth of a Two-Dimensional Halide Perovskite Ferroelectric for Highly Polarized-Sensitive Photodetection^※[J]. Acta Chimica Sinica, 2022, 80(3): 237-243.

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Fig. & Tab. 6

Figure 1. (a) Photograph of crystals (iPA)2EA2Pb3I10. (b) Simulated crystal morphology of (iPA)2EA2Pb3I10. (c) The crystal structure of (iPA)2EA2Pb3I10 (the blue arrow shows the direction of ferroelectric polarization)

Figure 2. P-E hysteresis loop of (iPA)2EA2Pb3I10晶体

Figure 3. The ultraviolet-visible absorption optical spectra and fluorescence spectra of (iPA)2EA2Pb3I10 (insert shows the diffuse reflection spectrum)

Figure 4. (a) I-V curves of (iPA)2EA2Pb3I10 under 637 nm laser irradiation with different optical power. (b) Photovoltaic effect of (iPA)2EA2Pb3I10

Figure 5. (a) Polarizaiton-sensitive photodetector based on (iPA)2EA2Pb3I10 crystals; photocurrent-angle curve under polarized light with different wavelength: (b) 405 nm; (c) 520 nm; (d) 637 nm (under zero bias)

Figure 6. (a) Temporal photoresponse with the rise/decay times of 210 and 429 µs, respectively. (b) Repetitive switching cycles of photoresponse. Responsibility (c) and photodetectivity (d) of polarizaiton-sensitive photodetector based on (iPA)2EA2Pb3I10 crystals under weak polarized light with different power intensity

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大尺寸二维卤化物钙钛矿铁电晶体的生长及偏振光电探测性能研究^※

Bulk Single Crystal Growth of a Two-Dimensional Halide Perovskite Ferroelectric for Highly Polarized-Sensitive Photodetection^※

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大尺寸二维卤化物钙钛矿铁电晶体的生长及偏振光电探测性能研究※

Bulk Single Crystal Growth of a Two-Dimensional Halide Perovskite Ferroelectric for Highly Polarized-Sensitive Photodetection※

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Supporting Info.

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Abstract

Cite this article

share this article

Fig. & Tab. 6

References 37

Related Articles 15

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大尺寸二维卤化物钙钛矿铁电晶体的生长及偏振光电探测性能研究^※

Bulk Single Crystal Growth of a Two-Dimensional Halide Perovskite Ferroelectric for Highly Polarized-Sensitive Photodetection^※