Acta Chimica Sinica ›› 1955, Vol. 21 ›› Issue (3): 227-231. Previous Articles     Next Articles

贝母植物硷研究Ⅱ.贝母素甲及乙的再研究

朱子清1,2, 陆仁荣1,2   

  1. 1. 中国科学院有机化学研究所;
    2. 復旦大学化学系
  • 投稿日期:1955-04-09 发布日期:2013-06-04

A STUDY OF FRITILLARIA ALKALOIDS Ⅱ. FURTHER STUDY OF PEIMINE AND PEIMININE

CHU TZE-TSIN(T. T. CHU)1,2, LOH JEN-YUNG1,2   

  • Received:1955-04-09 Published:2013-06-04

The empirical formulae of peimine and peiminine are revised to C27H45O3N and C27H43O3N respectively.Neither peimine nor peiminine has a methoxyl or ethoxyl group, a methylimino or ethylimino group, or probably a tertiary alcoholic hydroxyl group.Their basic tertiary nitrogen atomis probably present in the bicyclic ring.Peimine or peiminine has no active ethylenic linkage, and the active methylene group adjacent to the carbonyl group of peiminine seems to be absent.Both peimine and peiminine contain at least three carbon-methyl groups and give no sparingly soluble digitonide.