Acta Chimica Sinica ›› 1961, Vol. 27 ›› Issue (3): 214-218. Previous Articles    

聚甲基丙烯酸甲酯混合溶剂体系 Ⅳ. 交联聚合物在混合溶剂中的溶胀

程镕时1, 秦汶1, 钱人元2   

  1. 1. 中国科学院应用化学研究所;
    2. 中国科学院化学研究所
  • 投稿日期:1960-08-04 发布日期:2013-06-03

POLYMETHYLMETHACRYLATE IN MIXED SOLVENTS Ⅳ. EQUILIBRIUM SWELLING OF A SLIGHTLY CROSSLINKED POLYMER IN MIXED SOLVENTS

CHENG YUNG-SHIH1, CHING WEN1, CHIEN JEN-YUAN2   

  1. 1. Institute of Applied Chemistry, Academia Sinicu;
    2. Institute of Chemistry, Academia Sinica
  • Received:1960-08-04 Published:2013-06-03

The equilibrium swelling ratios of a slightly crosslinked polymethylmethacrylate sample in toluene-ethanol and acetone-water solvent-non-solvent mixtures have been determined volumitrically, The values of swelling ratio Q go through a maximum at the volume fraction of the non-solvent, γ=0.1%(ethanol) and 0.02(water) for the two systems respectively, in parallel with the viscornetric and osmometric behavior observed in dilute solutions.