Acta Chimica Sinica ›› 1964, Vol. 30 ›› Issue (2): 197-204. Previous Articles     Next Articles

硫醇对炔属化合物的加成反应Ⅲ.苯硫酚与硫醇乙酸对β-烷基苯乙炔的加成

刘有成, 张自义   

  1. 兰州大学化学系
  • 收稿日期:1963-07-22 出版日期:1964-04-15 发布日期:2013-06-03

THE ADDITION OF THIOLS TO ACETYLENIC COMPOUNDS Ⅲ. THE ADDITION OF THIOPHENOL TO β-ALKYLPHENYLACETYLENES

LIU YU-CHENG, CHANG TZI-YI   

  1. Department of Chemistry, Lanchow University
  • Received:1963-07-22 Online:1964-04-15 Published:2013-06-03

Under the initiation of benzoyl peroxide or ultraviolet light,thiophenol added smoothly to 1-phenylpropyne-1 and to 1-phenylbutyne-1.When equimolecular ratio of the reactants was used,the addition products were 1-phenyl-2-phenylthiopropene-1 (Ⅰ) and 1-phenyl-2-phenylthiobutene-1 (Ⅱ),respectively.When the amount of thiophenol used was doubled,there were obtained,besides the one-to-one adducts named,two-to-one adducts; 1-phenyl-2,2-di-(phenylthio)-propane (V) and 1-phenyl-2,2-di-(phenylthio)-butane (Vr),respectively.