Acta Chimica Sinica ›› 1964, Vol. 30 ›› Issue (2): 197-204.
LIU YU-CHENG, CHANG TZI-YI
Under the initiation of benzoyl peroxide or ultraviolet light,thiophenol added smoothly to 1-phenylpropyne-1 and to 1-phenylbutyne-1.When equimolecular ratio of the reactants was used,the addition products were 1-phenyl-2-phenylthiopropene-1 (Ⅰ) and 1-phenyl-2-phenylthiobutene-1 (Ⅱ),respectively.When the amount of thiophenol used was doubled,there were obtained,besides the one-to-one adducts named,two-to-one adducts; 1-phenyl-2,2-di-(phenylthio)-propane (V) and 1-phenyl-2,2-di-(phenylthio)-butane (Vr),respectively.
LIU YU-CHENG, CHANG TZI-YI. THE ADDITION OF THIOLS TO ACETYLENIC COMPOUNDS Ⅲ. THE ADDITION OF THIOPHENOL TO β-ALKYLPHENYLACETYLENES[J]. Acta Chimica Sinica, 1964, 30(2): 197-204.
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