Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (5): 421-425.     Next Articles

Original Articles

双[N-(R)-α-甲苄基水杨醛亚氨基]铜(II)配合物的晶体结构和分子结构

李根培;杨清传;唐有祺;关烨娣;尚振海   

  1. 北京大学物理化学研究所;北京大学化学系
  • 发布日期:1987-05-15

The crystal and molecular structure of bis[N-(R)-\a\-methylbenzyl salicylaldiminato]copper(II) complex

LI GENPEI;YANG QINGCHUAN;TANG YOUQI;GUAN YEDI;SHANG ZHENHAI   

  • Published:1987-05-15

The title complex is orthorhombic, space group P212121, with a 0.8844(2), b 1.6286(4), and c 1.7751(5) nm; dc = 1.33 for Z = 4. Final R = 5.8% (Rw = 4.7%) for 2604 reflections. Atomic coordinates are given. The Cu environment of the complex is a distorted tetrahedral conformation. The angle between the plane defined by the N(1)-Cu-O(1) and N(2)-Cu-O(2) groups is ~39.3? The a-methylbenzyl groups point to the same side of the approx. Cu,N(1),O(1),N(2),O(2) ligand plane (cis), and they are roughly perpendicular to the remainder of the mol. and roughly perpendicular to each other.

Key words: PHENOL P, CRYSTAL STRUCTURE DETERMINATION, MOLECULAR STRUCTURE, UNIT CELL, COPPER COMPLEX, TRANSITION METAL COMPLEX, MESOTOMY, SCHIFF BASE, BENZENEMETHANAMINE P, LEAST SQUARE METHODS

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