Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (12): 1153-1158. Previous Articles     Next Articles

Original Articles

绝热式热动力学的研究III:二级反应的热谱解析

詹曙光;杨明利;邓郁;代厚全;代厚全;安慕晖   

  1. 四川大学分析测试中心;四川师范大学分析测试中心;中国科学院上海有机化学研究所
  • 发布日期:1990-12-15

Studies ofn adiabatic thermokinetics III: thermokinetic research of second-order reactions

ZHAN SHUGUANG;YANG MINGLI;DENG YU;DAI HOUQUAN;DAI HOUQUAN;AN MUHUI   

  • Published:1990-12-15

An adiabatic thermokinetic research method for second-order reactions is proposed. The thermogram anal. of one endothermal reaction and three exothermal reactions have been undertaken with this method. The calculated rate constants of these reactions agree with those reported in literature.

Key words: SODIUM COMPOUNDS, ETHANOL, SUBSTITUTION REACTION, ETHYL ESTER, BENZENECARBOXYLIC ACID P, ACETIC ACID, CALORIMETRY, NUCLEOPHILIC REACTION, SAPONIFICATION, ANALYTIC

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