Acta Chimica Sinica ›› 1996, Vol. 54 ›› Issue (6): 568-574. Previous Articles     Next Articles

Original Articles

三水合高氯酸镨与18-冠-6配合的研究

薛岗林;李谦定;胡少明;徐宏;任德厚;张泉珍   

  1. 西北大学化学系;西北大学热化学研究室
  • 出版日期:1996-06-15 发布日期:1996-06-15

Study on complexes of trihydrated praseodymium perchlorate with 18 -crown-6

XUE GANGLIN;LI QIANDING;HU SHAOMING;XU HONG;REN DEHOU;ZHANG QUANZHEN   

  • Online:1996-06-15 Published:1996-06-15

The solubilities of the ternary system, Pr(ClO4)3.3H2O-18C6- C2H5OH, have been investigated by a semimicro method at 298.15K for study of phase equilibrium and the refractive indexes of saturated solutions have been determined. The results indicate that there are two kinds of coordination compounds formed in the system, their chemical compositions are: Pr(ClO4)3.18C6.3H2O(1) and Pr(ClO4)3.2(18C6).3H2O(2). The two solid coordination compounds have been prepared. The composition and properties of the complexes have been investigated by chemical analysis, IR, TG and DTG. The integral heats of solution of Pr(ClO4)3.3H2O in 18C-C2H5OH solution, the complexes (1) and (2) in C2H5OH, and 18C6 in C2H5OH have been measured calorimetrically at 298.15K. By means of a thermochemical cycle suggested in this paper, the standard molar enthalpies of formation for two complexes were obtained.

Key words: PHASE EQUILIBRIUM, INFRARED SPECTROPHOTOMETRY, TERNARY SYSTEM, CROWN ETHER COMPOUNDS, ENTHALPY OF FORMATION, PERCHLORATE, PRASEODYMIUM COMPLEX

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