Acta Chimica Sinica ›› 1999, Vol. 57 ›› Issue (3): 281-288.

Original Articles

### 毛细管电泳分离过程的不可逆热力学模型及优化控制仿真

1. 西安交通大学轴承研究所;西安交通大学化工学院
• 出版日期:1999-03-15 发布日期:1999-03-15

### Irreversible thermodynamics in capillary electrophoresis separation process and optimal control

Li Yaping;Yu Lie;Xie Youbai;Liang Heng

• Online:1999-03-15 Published:1999-03-15

In this paper, on the basis of nonequilibrium thermodynamics separation theory, the separation model of capillary electrophoresis is established. Taking the operating voltage U as controllable parameter, the net separation entropy S~S of solute system as objective function, by optimal design of the separation big system, the optimizing control orbit U^*(t) can be obtained. By simulation, the separation efficiency of the system under the control of U^*(t) can reach to the expected results.

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