Synthesis of New Cuniform Molecular Host Model Based on β- Cyclodextrin

Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (8): 1536-1538. Previous Articles Next Articles

Original Articles

用环糊精合成楔筒状主体分子新模型

郝爱友;王金山

山东大学化学与化工学院,济南(250100);山东师范大学化学系,济南(250014)

发布日期:2002-08-15

Synthesis of New Cuniform Molecular Host Model Based on β- Cyclodextrin

Hao Aiyou;Wang Jinshan

School of Chemistry & Chemical Engineering, Shandong University, Jinan(250100);Department of Chemistry, Shandong Normal University, Jinan(250014)

Published:2002-08-15

Abstract

β-Cyclodextrin with the 6-hydroxyls protected by dimethyl-tert- butylsilyl was selectively oxidized by lead tetraacetate. After the silyl groups were removed off by boron fluoride-etherate, mono-2,3- dialdehydro-β-cyclodextrin as a cuniform molecule could be constructed. Mono-2,3-dialdehydro-β-cyclodextrin is more soluble in water than β- cyclodextrin. Mono-2,3-dialdehydo-β-cyclodextrin could be used as the mobile phase additives for effective resolution of DL-adrenaline on silica gel plates.

Key words: CYCLODEXTRIN, MACROCYCLIC COMPOUNDS, EPINEPHRINE, ENANTIOMORPH

CLC Number:

O621

Cite this article

Hao Aiyou;Wang Jinshan. Synthesis of New Cuniform Molecular Host Model Based on β- Cyclodextrin[J]. Acta Chimica Sinica, 2002, 60(8): 1536-1538.

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用环糊精合成楔筒状主体分子新模型

Synthesis of New Cuniform Molecular Host Model Based on β- Cyclodextrin

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