Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (9): 1508-1510. Previous Articles     Next Articles

Original Articles

利用腙类化合物作为检测阴离子的敏感器

周丽丽;张晓宏;吴世康   

  1. 中国科学院理化技术研究所
  • 发布日期:2003-09-15

Hydrazone Compounds Used as Sensor for Detection of Anions

Zhou Lili;Zhang Xiaohong;Wu Shikang   

  1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences
  • Published:2003-09-15

The interaction between four compounds containing hydrogen bond donors and anionic species have been investigated. It is found that hydrazone (2) with a nitrogroup has excellent ability for the detection of fluoride anion. Although on the contrary, hydrazone (3) with hydroxy group can sense fluoride anion, its selectivity is poor, but it can detect the presence of dihydrogenphosphate anions. As for the Schiff base compound (4), it have no remarkable properties to be used as an anion sensor. The experimental results are discussed preliminary. Some consideration concerned to improve the sensitivity and selectivity of these compounds is suggested.

Key words: HYDRAZONE, COLORIMETRIC METHOD, HYDROGEN BONDS, INTERACTIONS, FLUORINE ION

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