Study on Spectral Characterization of Water Soluble Chiral Salen Mn(Ⅲ) Complexes and the Recognition of Amino Acids

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (1): 58-65. Previous Articles Next Articles

水溶性手性Salen Mn(Ⅲ)的光谱性质及其对氨基酸客体的分子识别研究

朱必学, 阮文娟, 高峰, 胡国航, 朱志昂

南开大学化学系, 天津, 300071

投稿日期:2003-05-12 修回日期:2003-09-11 发布日期:2014-01-26
通讯作者: 朱志昂 E-mail::E-mail:zazhu@nankai.edu.cn
基金资助:
国家自然科学基金(Nos.20171024,20271030)、天津市自然科学基金(No.023604011)及教育部留学回国人员科研基金资助项目.

Study on Spectral Characterization of Water Soluble Chiral Salen Mn(Ⅲ) Complexes and the Recognition of Amino Acids

ZHU Bi-Xue, RUAN Wen-Juan, Gao Feng, HU Guo-Hang, ZHU Zhi-Ang

Department of Chemistry, Nankai University, Tianjin 300071

Received:2003-05-12 Revised:2003-09-11 Published:2014-01-26

Abstract

The chiral salen H 2 and chiral salen Mn(Ⅲ) complex were synthesized and characterized. The infrared spectra, electronic absorption spectra and circular dichroism spectra properties were discussed. The results show that the conformation of five-coordinate salen Mn(Ⅲ) complex is Δ in water solution. The associative constants (K) of the molecular recognition reactions were determined by means of UV-vis spectral titration technique. And the order of K are K_D>K_L and K(Phe)>K(Val)>K(Thr). Circular dichroism (CD) spectra were studied and the results are consistent with that from the thermodynamics of association reaction of the host-guest system.In addition,the conformations with minimal energy of salen Mn(Ⅲ) and each host-guest molecular system were sought by simulated annealing method. Quantum chemical calculations were performed based on these conformations to explain the experimental data.

Key words: salen Mn(III), amino acid ligand, spectrum, molecular recognition, molecular mechanics

Cite this article

ZHU Bi-Xue, RUAN Wen-Juan, Gao Feng, HU Guo-Hang, ZHU Zhi-Ang . Study on Spectral Characterization of Water Soluble Chiral Salen Mn(Ⅲ) Complexes and the Recognition of Amino Acids[J]. Acta Chimica Sinica, 2004, 62(1): 58-65.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Zhou, X.; Shearer, J.; Rokita, S. E. J. Am. Chem.Soc. 2000, 122, 9046.
[2] Liu, J.-G.; Zhang, Q.-L.; Shi, X.-F.; Ji, L.-N. Inorg. Chem. 2001, 40, 5045.
[3] Onfelt, B.; Lincoln, P.; Norden, B. J. Am. Chem. Soc. 2001, 123, 3630.
[4] Dennis, J. G.; Griffin, J. H. J. Inorg. Chem. 1996, 35, 4837.
[5] Wang, C.-Z.; Zhu, Z.-A.; Li, Y.; Che, R.-T.; Wen, X.; Miao, F.-M.; Che, X.-C. Chem. J. Chin. Univ. 2001, 22(2), 262 (in Chinese).(王传忠, 朱志昂, 李瑛, 陈荣悌, 文欣, 缪方明, 陈新滋, 高等学校化学学报, 2001, 22(2), 262.)
[6] You, T.-B. Modern Research Methods of Chiral Compounds, University of Chinese Science and Technology Press, Hefei, 1993, p. 229 (in Chinese).(尤田耙著, 手性化合物的现代研究方法, 中国科技大学出版社, 合肥, 1993, p. 229.)
[7] Kuroda, Y; Kato, Y.; Higashioji, T.; Hasegawa, J. Y.; Kawanami, S.; Takahashi, M.; Shiraishi, N.; Tanabe, K.; Ogoshi, H. J. Am. Chem. Soc. 1995, 117, 10950.
[8] Zhang, Y.-L.; Ruan, W.-J.; Li, Y.; Nan, J.; Zhu, Z.-A. Acta Chim. Sinica 2003, 61(2), 186 (in Chinese).(张玉玲, 阮文娟, 李瑛, 南晶, 朱志昂, 化学学报, 2003, 61(2), 186.)
[9] Larrow, J. F.; Jacobsen, E. N. Org. Chem. 1994, 59, 1939.
[10] Zamian, J. R.; Dockal, E. R. Trans. Met. Chem. 1996, 21, 370.
[11] Signorini, O.; Dockal, E. R.; Castellano, G.; Oliva, G. Polyhedron 1996, 15, 245.
[12] Sliverstein, R. M.; Bassler, G. C.; Morril, T. C. Spectrometric Identification of Organic Compunds, 5th ed., John Wiley and Son, New York, 1991, p. 289.
[13] Zolezzi, S.; Decinti, A.; Spodine, E. Polyhedron 1999, 18, 897.
[14] Bosnich, B. J. Am. Chem. Soc. 1968, 90, 627.
[15] Crawford, S. M. Spectrochim. Acta 1963, 19, 255.
[16] Sheat, S. V.; Waters, T. N. J. Inorg. Nucl. Chem. 1968, 909, 627.
[17] Richard, L. F.; Urbach, F. Inorg. Chem. 1970, 9, 2562.
[18] Smith, H. E.; Neergaard, J. R.; Burrows, E. P.; Chen, F. M. J. Am. Chem. Soc. 1974, 96, 2908.
[19] Busetto, C.; Cariati, F.; Fusi, A.; Gullotti, M.; Morazzoni, F.; Pasini, A.; Ugo, R.; Valenti, V. J. Chem. Soc. Dalton Trans. 1973, 754.
[20] Pasini, A.; Gullotti, M. J. Chem. Soc., Dalton Trans. 1977, 346.
[21] Downing, R. S.; Urbach, F. L. J. Am. Chem. Soc. 1968, 91, 5977.
[22] Zheng, K.-C.; Rao, H.-Y.; He, F. Acta Phys.-Chim. Sin. 1998, 14(2), 299 (in Chinese).(郑康成, 饶火瑜, 何峰, 物理化学学报, 2002, 14(2), 299.)
[23] Ji, G.-F.; Xiao, H.-M.; Dong, H.-S. Acta Chim. Sinica 2002, 59(1), 39 (in Chinese).(姬广富, 肖鹤鸣, 董海山, 化学学报, 2002, 59(1), 39.)

水溶性手性Salen Mn(Ⅲ)的光谱性质及其对氨基酸客体的分子识别研究

Study on Spectral Characterization of Water Soluble Chiral Salen Mn(Ⅲ) Complexes and the Recognition of Amino Acids

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Shouming Cheng, Bo Zhou. Molecular Insights into the Transformation Mechanisms of Dissolved Organic Matter Based on Ultrahigh Resolution Mass Spectrometry [J]. Acta Chimica Sinica, 2022, 80(8): 1106-1114.
[2]	Bo Yifan, Liu Yuyu, Chang Yongzheng, Li Yinxiang, Zhang Xiaofei, Song Chunyuan, Xu Weifeng, Cao Hongtao, Huang Wei. Theoretical and Experimental Studies on Raman Spectroscopy of Cyclic Fluorene-Based Strained Semiconductors [J]. Acta Chim. Sinica, 2019, 77(5): 442-446.
[3]	Wang Bin, Wang Jianfu, Zhang Xiaofei, Chen Wenjie, Zhang Yongfan, Huang Xin. Theoretical Investigations on the Structures and the Chemical Bonding of NbMoS_n^-/0 (n=3~7) Clusters [J]. Acta Chim. Sinica, 2017, 75(3): 307-320.
[4]	Zhao Zigang, Niu Yongqiang, Zhao Yang, Song Qinghua, Xin Ling, Lu Xiaoqing. First-Principles Theory Investigation on Structural and Photoelectronic Properties of Formamidinium Lead Halide Perovskites [J]. Acta Chim. Sinica, 2016, 74(8): 689-693.
[5]	Rong Genlan, Zhang Xinyi, Xu Yan, Zhang Yuegang. In-situ TEM Study of the Liquid-Phase Reaction of Ag Nanowires with a Sulfur Solution [J]. Acta Chim. Sinica, 2016, 74(12): 980-983.
[6]	Zhang Mingjing, Pan Qingjiang, Guo Yuanru, Zhang Hongxing. Electronic Structures and Spectroscopy of Pyridyl Ru-phthalocyanine Photosensitizers [J]. Acta Chimica Sinica, 2014, 72(6): 697-703.
[7]	Jiang Yuqian, Xu Haihua, Zhao Ni, Peng Qian, Shuai Zhigang. Spectral Signature of Intrachain and Interchain Polarons in Donor-Acceptor Copolymers [J]. Acta Chimica Sinica, 2014, 72(2): 201-207.
[8]	Lv Jiangtao, Yang Linjuan, Li Zhigang, Wei Yongtao, Zhang Baojian, Liang Liqin, Wang Fengwen, Si Guangyuan . Resonance Tuning in Plasmonic Nanorods for Enhanced Infrared Spectrum Detecting [J]. Acta Chimica Sinica, 2013, 71(9): 1275-1280.
[9]	Shi Qinghua, Peng Qian, Sun Shaorui, Shuai Zhigang. Vibration Correlation Function Investigation on the Phosphorescence Quantum Efficiency and Spectrum for Blue Phosphorescent Ir(III) Complex [J]. Acta Chimica Sinica, 2013, 71(06): 884-891.
[10]	Ye Suyu, Peng Liang, Song Kesheng, Gu Fenglong. Halogen Doping Effect on Electronic Structure of Poly(methylphenyl)silane: a Theoretical Study [J]. Acta Chimica Sinica, 2013, 71(02): 271-278.
[11]	Zhang Yujian, Xie Bin, Zhang Liyang, Ma Li, He Shuyan, Li Guowen. Preparation and Properties of Amphiphilic Polymer Nanospheres Containing Aza-crown ether [J]. Acta Chimica Sinica, 2012, 0(04): 499-504.
[12]	Fan Jianfeng, Zhao Chenxing, Fan Louzhen. Preparation and Mechanism of Nest-like Ag Microcrystals and Their Surface Enhanced Raman Spectroscopic Studies [J]. Acta Chimica Sinica, 2012, 70(03): 229-234.
[13]	CHEN Zi-Ran, NIE Han, LI Quan, ZHAO Ke-Qing. Electronic spectrum and the secord-order nonlinear optical properties of pyrazoline- oxadiazole organic molecules [J]. Acta Chimica Sinica, 2011, 69(24): 2908-2914.
[14]	CUI Qing-Hua, SHAO Yong, MA Kun, LIU Gui-Ying, WU Fei, XU Shu-Juan. Study on Recognition of Single-nucleotide Polymorphism based on Fluorescence Enhancement of Terbium Ion upon Binding at an Abasic Site in DNA [J]. Acta Chimica Sinica, 2011, 69(18): 2137-2142.
[15]	ZHANG Yu-Yang, LI Ying-Ying, ZHAO Kun, ZHAO Ling, ZANG Shu-Liang. CdTe Quantum Dots as a Probe for Interaction between Salmon Sperm DNA and Riboflavin [J]. Acta Chimica Sinica, 2011, 69(16): 1951-1956.