Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (17): 1649-1652. Previous Articles     Next Articles

中氮茚腈类化合物的合成及其荧光性质的研究

王炳祥1,2, 沈永淼1, 沈健1,2, 李邨1, 胡宏纹3   

  1. 1.南京师范大学化学与环境科学学院, 南京, 210097;
    2.江苏省生物医药功能材料工程研究中心, 南京, 210097;
    3. 南京大学化学系, 南京, 210093
  • 投稿日期:2003-12-01 修回日期:2004-05-28 发布日期:2014-02-17
  • 通讯作者: wabx@jlonline.com
  • 作者简介:王炳祥,E-mail:wabx@jlonline.com
  • 基金资助:
    国家自然科学基金(No.20072016)资助项目.

Synthesis and Fluorescence Properties of Indolizines Substituted with Cyano Groups

WANG Bing-Xiang1,2, SHEN Yong-Miao1, SHEN Jian1,2, LI Chun1, HU Hong-Wen3   

  1. 1. College of Chemistry and Environment Science, Nanjing Normal University, Nanjing 210097;
    2. Jiangsu Research Center of Biomedical Functional Materials Engineering, Nanjing 210097;
    3. Department of Chemistry, Nanjing University, Nanjing 210093
  • Received:2003-12-01 Revised:2004-05-28 Published:2014-02-17

A series of indolizines were synthesized.The fluorescence spectra and fluorescence quantum yields of the compounds 3a~3k, 4a~4b and 5~6 were examined.It was found that the quantum yields increased if the cyano group was introduced into the indolizines, while the presence of carbonyl groups as substituents of indolizines resulted in fluorescence quenching.The indolizines 3a~3b and 3g~3i with high fluorescence quantum yields are shown to be useful fluorophores to the construction of probe compounds.

Key words: indolizine,fluorescence spectrum,fluorescence quantum yield