Study on the Photoactivated Mechanism of a Kind of Photoactivated Pesticide, Pyrophaeophorbide-a

Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (1): 17-21. Previous Articles Next Articles

焦脱镁叶绿酸-a作为光活化农药的光活化机理研究

吴铁一¹^{,3，屠铁城¹，赵红卫¹，陈志龙²，姚思德*^,1}

(¹中国科学院上海应用物理研究所上海 201800)
(²中国人民解放军第二军医大学海军医学系上海 200433)
(³北京健之素医药科技有限公司北京 102209)

投稿日期:2005-04-18 修回日期:2005-09-12 发布日期:2006-01-14
通讯作者: 姚思德

Study on the Photoactivated Mechanism of a Kind of Photoactivated Pesticide, Pyrophaeophorbide-a

WU Tie-Yi¹^{,3, TU Tie-Cheng¹, ZHAO Hong-Wei¹, CHEN Zhi-Long², YAO Si-De*^,1}

(¹Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800)
(² Faculty of Naval Medicine, Second Military Medical University, Shanghai 200433)
(³ Beijing Health Essence Medical Science Technology Co., Ltd, Beijing 102209)

Received:2005-04-18 Revised:2005-09-12 Published:2006-01-14
Contact: YAO Si-De

Abstract

Possibility of pyrophaeophorbide-a to be a kind of photoactivated pesticide was presented. Its photoactivated mechanism was studied by use of time-resolved laser flash photolysis and spin trapped EPR technique. It is found that Type II path (singlet oxygen) exists. And the interaction between singlet oxygen and three kinds of biological molecules (DNA, linoleic acid and L-tryptophan) was also studied.

Key words: pyrophaeophorbide-a, photoactivated pesticide, singlet oxygen, electron paramagnetic resonance

Cite this article

WU Tie-Yi^1,3, TU Tie-Cheng, ZHAO Hong-Wei, CHEN Zhi-Long², YAO Si-De*^,1. Study on the Photoactivated Mechanism of a Kind of Photoactivated Pesticide, Pyrophaeophorbide-a[J]. Acta Chimica Sinica, 2006, 64(1): 17-21.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Xiaojuan Li, Ziyu Ye, Shuhan Xie, Yongjing Wang, Yonghao Wang, Yuancai Lv, Chunxiang Lin. Study on Performance and Mechanism of Phenol Degradation through Peroxymonosulfate Activation by Nitrogen/Chlorine Co-doped Porous Carbon Materials [J]. Acta Chimica Sinica, 2022, 80(9): 1238-1249.
[2]	Long Saran, Wan Yan, Xia Andong. Spectral Properties of Water-Soluble Conjugated Polymer PFP/DNA/Porphyrin Complex [J]. Acta Chim. Sinica, 2015, 73(7): 723-728.
[3]	. Investigation of Free Radical Intermediates of Formaldehyde Photocatalytic Degradation by Electron Paramagnetic Resonance [J]. Acta Chimica Sinica, 2009, 67(7): 671-674.
[4]	ZHOU Jun^1,2 WU Ke³ SUN Yue² CONG Jian-Bo³ WANG Chang-Zhen³ CHANG Xiang² XIAN Hong³ ZHU Yong-Fa*^,1. A Novel Method for Quantitative Analysis of Total Particulate-phase Free Radicals in Mainstream Cigarette Smoke [J]. Acta Chimica Sinica, 2008, 66(2): 216-222.
[5]	Zhou Weishan;Xu Xingxiang. Total synthesis of the antimalarial sesquiterpene peroxide Qinghaosu and Yingzhaosu A [J]. Acta Chimica Sinica, 2000, 58(2): 135-143.
[6]	Sun Wenfang;DONG SHIMING;WANG DUOYUAN;LE JIACHANG;WAN QIAN;LI MEIFEN;PANG SUZHEN. Chemistry of singlet oxygen VIII. ESR studies of singlet oxygen generated by photosensitization of porphyrin-like rare earth complexes [J]. Acta Chimica Sinica, 1997, 55(7): 665-671.
[7]	WANG DUOYUAN;CHANG JING. Singlet oxygen chemistry. VII. the quenching of singlet oxygen by the main antioxidative components of rosemary [J]. Acta Chimica Sinica, 1994, 52(3): 301-305.
[8]	WANG NENGHUI;AN JINGYI;JIANG LIJIN. Inhibition of singlet oxygen production from photosensitized hypocrellin A by reducing bilogical molecules. [J]. Acta Chimica Sinica, 1992, 50(9): 905-909.
[9]	JIANG ZHIQIN;WANG YAN. Studies on photooxidation [J]. Acta Chimica Sinica, 1991, 49(2): 205-208.
[10]	LIU XINHOU;LIU RUOZHUANG. On the mechanisms of photosensitized oxygenation of olefins II: Reaction ergodography for [2+2] cycloaddition of singlet oxygen to propylene [J]. Acta Chimica Sinica, 1989, 47(3): 308-311.
[11]	JIANG ZHIQIN;ZENG DAIXUN;LIU YOUCHENG. Singlet oxygen photooxidation of cholesterol sensitized by lumiflavin [J]. Acta Chimica Sinica, 1989, 47(2): 194-198.
[12]	CHEN DONGLI;WANG DUOYUAN;XIAO XULING. Singlet oxygen chemistry IV: Sensitized photooxygenation of 6-substituted-1,4-cyclooctadienes [J]. Acta Chimica Sinica, 1989, 47(2): 147-151.
[13]	CHEN DONGLI;HE HUIZHU;LI QIONGYAO;XIAO XULING;WANG DUOYUAN. Singlet oxygenation of cis, cis-1,5-cyclooctadiene and thermal rearrangement of product [J]. Acta Chimica Sinica, 1988, 46(8): 791-795.
[14]	WANG DUOYUAN;ZHOU JINGSHI. Reaction of trans, trans, cis-2,4,7-tetradecatriene with singlet oxygen [J]. Acta Chimica Sinica, 1987, 45(8): 825-828.
[15]	WU SHIKANG;ZHANG HOUCHEN;CUI GUOZHU;XU DANIAN;XU HUIJUN. A study on the ability of some phthalocyanine compounds for photo-generating singlet oxygen [J]. Acta Chimica Sinica, 1985, 43(1): 10-13.

焦脱镁叶绿酸-a作为光活化农药的光活化机理研究

Study on the Photoactivated Mechanism of a Kind of Photoactivated Pesticide, Pyrophaeophorbide-a

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments