Acta Chimica Sinica ›› 2010, Vol. 68 ›› Issue (11): 1123-1129. Previous Articles     Next Articles

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有机染料敏化网状二氧化钛纳米纤维微孔膜太阳能电池研究

冯小明1,黄先威1,黄辉1,沈平1,赵斌1,2,谭松庭*,1,2   

  1. 1湘潭大学化学学院与湖南省高校先进功能高分子材料重点实验室 湘潭 411105)
    (2教育部环境友好化学与应用重点实验室 湘潭 411105
  • 收稿日期:2009-11-08 修回日期:2010-01-08 出版日期:2010-06-14 发布日期:2010-01-25
  • 通讯作者: 谭松庭 E-mail:Tanst2008@163.com

Study of the TiO2 Nanofibers Network Microporous Film for Organic Dye-sensitized Solar Cells

Feng Xiaoming1 Huang Xianwei1 Huang Hui1 Shen Ping1 Zhao Bin1,2 Tan Songting*,1,2   

  1. (1 College of Chemistry and Key Laboratory of Advanced Functional Polymeric Materials of College of Hunan Province, Xiangtan University, Xiangtan 411105)
    (2 Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, Xiangtan 411105)
  • Received:2009-11-08 Revised:2010-01-08 Online:2010-06-14 Published:2010-01-25

A novel composite photoanode for dye-sensitized solar cells (DSSCs) was fabricated by electrospinning the TiO2 nanofibers onto the TiO2 nanoparticles as a light scattering layer. The magnesium oxide (MgO) was doped in the TiO2 nanoparticles in order to suppress the recombination of electron and hole. When the composite photoanodes were sensitized by using the organic triphenylamine dyes (SD2, SD3) or a ruthenium dye (N719) with the co-adsorbent chenodeoxycholic acid (CDCA), the high power conversion efficiency (η) of 6.35%~8.85% was obtained under simulated AM 1.5 irradiation (100 mW/cm2). Meanwhile, the power conversion efficiency of the quasi-solid DSSCs reached about 90% that of liquid electrolyte DSSCs.

Key words: electrospun, microporous membrane, dye-sensitized solar cells, power conversion efficiency