Synthesis, characterization and structure of the coordination compounds [(C12H24O6)NH4]2UO2(NCS)4H2O and [(C12H24O6)K]2UO2-(NCS)4H2O

Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (6): 548-556. Previous Articles Next Articles

Original Articles

硫氰酸铀铣(18-冠-6)铵(或钾)配合物的合成, 特性和结构

张静智;陈忠;杨永会;汪明;郑培菊

山东大学化学系;复旦大学分析测试中心

发布日期:1989-06-15

Synthesis, characterization and structure of the coordination compounds [(C12H24O6)NH4]2UO2(NCS)4H2O and [(C12H24O6)K]2UO2-(NCS)4H2O

ZHANG JINGZHI;CHEN ZHONG;YANG YONGHUI;WANG MING;ZHENG PEIJU

Published:1989-06-15

Abstract

[K(18-crown-6)]2[UO2(NCS)4(H2O)] (II) were prepared and characterized by x-ray crystallog., IR and UV. I crystd. in orthorhombic space group Fdd2 and II in monoclinic space group C2/c. Their solubilities in some organic solvents is discussed.

Key words: ULTRAVIOLET SPECTROPHOTOMETRY, CRYSTAL STRUCTURE DETERMINATION, INFRARED SPECTROPHOTOMETRY, X-RAY DIFFRACTION ANALYSIS, URANYL COMPOUNDS, CROWN ETHER COMPOUNDS, THIOCYANATE, POTASSIUM COMPLEX, AMMONIUM COMPLEX

CLC Number:

O611.662

Cite this article

ZHANG JINGZHI;CHEN ZHONG;YANG YONGHUI;WANG MING;ZHENG PEIJU. Synthesis, characterization and structure of the coordination compounds [(C12H24O6)NH4]2UO2(NCS)4H2O and [(C12H24O6)K]2UO2-(NCS)4H2O[J]. Acta Chimica Sinica, 1989, 47(6): 548-556.

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硫氰酸铀铣(18-冠-6)铵(或钾)配合物的合成, 特性和结构

Synthesis, characterization and structure of the coordination compounds [(C12H24O6)NH4]2UO2(NCS)4H2O and [(C12H24O6)K]2UO2-(NCS)4H2O

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