Acta Chimica Sinica ›› 1996, Vol. 54 ›› Issue (1): 51-56. Previous Articles     Next Articles

Original Articles

冠硫醚化学Ⅵ: 生色冠硫醚的合成及其配合机理的研究

秦勇;杨季秋   

  1. 中国科学院成都有机化学研究所
  • 发布日期:1996-01-15

Thiacrown chemistryⅥ: Synthesis of chromogenic thiacrown and their coordination

QIN YONG;YANG JIQIU   

  • Published:1996-01-15

Four new chromogenic thiacrowns bearing 7-aza-1,4,10,13- tetrathiacyclohexadecane were successfully synthesized. The acid dissociation constants of chromogenic thiacrowns 3 and 4 were determined: pK~α=8.68(3); pK~a~1=8.49, pK~a~2=12.12(4). Their coordination to transitional metal cations were spectrophotometrically studied.

Key words: IONIZATION CONSTANT

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