Acta Chimica Sinica ›› 1996, Vol. 54 ›› Issue (2): 140-145. Previous Articles     Next Articles

Original Articles

Cl+HCl非反应截面和速率常数的TST-CEQ研究Ⅲ

陈德展;居冠之   

  1. 山东师范大学化学系;南京大学化学化工学院
  • 出版日期:1996-02-15 发布日期:1996-02-15

TST-CEQ study on nonreactive rate and cross section of Cl+HCl system

CHEN DEZHAN;JU GUANZHI   

  • Online:1996-02-15 Published:1996-02-15

The TST-CEQ method is generalized to calculate the nonreactive relaxed rate constants and average cross sections. The calculations are carried out by taking the reaction Cl+HCl as an example. The results compared with the literature show that this is feasible. In addition, the collinear reactive and nonreactive state to state rates are also given in the paper. It is shown that the nonreactive rates larger than the reactive ones at relatively low tempreature. And at high temperature the rates for reactive channel approach to the nonreactive ones, which indicates a competitive mechanism of the reaction.

Key words: HYDROGEN CHLORIDE, COLLISION CROSS-SECTIONS, KINETIC STUDY, RATE CONSTANTS, TST-CEQ

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