Studies on the electronic spectra of tris-(2,2'-bripyridine)and the first row of transition metal(II)complexes

Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (2): 163-168. Previous Articles Next Articles

Original Articles

第一过渡系金属M(II)的联吡啶配合物电子光谱的研究--谱带归属、D~q、B、β、ζ~3~d、λ

马立扬;郑耀东;林军建;盛葭林;龙星

湘潭大学化学系

发布日期:1992-02-15

Studies on the electronic spectra of tris-(2,2'-bripyridine)and the first row of transition metal(II)complexes

MA LYANG;ZHENG YAODONG;LIN JUNJIAN;SHENG JIALIN;LONG XING

Published:1992-02-15

Abstract

The tris(bipyridine) complexes of the bivalent metal ions (except Sc, Ti) of the 1st row of transition element were synthesized and their electronic absorption spectra were investigated extensively. Some important parameters of ligand field theory Dq, B, b, z3d and l are reported.

Key words: ZINC COMPLEX, STABILITY CONSTANT, IRON COMPLEX, COPPER COMPLEX, COBALT COMPLEX, TRANSITION METAL COMPLEX, NICKEL COMPLEX, BIPYRIDINE, ELECTRON TRANSITION, VANADIUM COMPLEX

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MA LYANG;ZHENG YAODONG;LIN JUNJIAN;SHENG JIALIN;LONG XING. Studies on the electronic spectra of tris-(2,2'-bripyridine)and the first row of transition metal(II)complexes[J]. Acta Chimica Sinica, 1992, 50(2): 163-168.

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第一过渡系金属M(II)的联吡啶配合物电子光谱的研究--谱带归属、D~q、B、β、ζ~3~d、λ

Studies on the electronic spectra of tris-(2,2'-bripyridine)and the first row of transition metal(II)complexes

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