Acta Chimica Sinica ›› 1991, Vol. 49 ›› Issue (6): 561-568. Previous Articles     Next Articles

Original Articles

2-甲基-,1-环丙烷二羧酸根乙二胺合铂(II)的晶体结构和振动光谱的简正坐标分析

倪亚萍;李重德;冯骏材;唐雯霞;周忠远   

  1. 南京大学配位化学研究所;中国科学院成都分院分析中心
  • 发布日期:1991-06-15

Crystal structure and normal coordinate analysis of 2-methyl-1,1,-cyclopropanedicarboxylate ethylenediamineplatinum (II)

NI YAPING;LI ZHONGDE;FENG JUNCAI;TANG WENXIA;ZHOU ZHONGYUAN   

  • Published:1991-06-15

The title compound is orthorhombic, space group Pn21a, with a 0.9075(4), b 1.0247(4), and c 1.1394(5) nm; Z = 4. The structure was solved by Patterson and Fourier techniques and refined by least-squares to R = 0.0706. The U-B force field was used in a normal coordinate anal. The calculated frequencies agree well with the observed values, with average difference 6.67 cm-1 between them. The frequencies were assigned in terms of potential energy distributions among force constants The rationality and the reliability of the result are discussed.

Key words: CRYSTAL STRUCTURE DETERMINATION, CYCLOPROPANE P, PLATINUM COMPLEX, VIBRATIONAL SPECTRA, LEAST SQUARE METHODS, ETHANEDIAMINE P, NORMAL COORDINATE ANALYSIS

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