Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (6): 535-542. Previous Articles     Next Articles

Original Articles

链状三核钼(钨)硫原子簇化合物[M3O2S8]^2^-的合成, 光谱和晶体结构

金国新;忻新泉;戴安邦;吴建华;王博义;郑培菊   

  1. 南京大学配位化学研究所;复旦大学分析测试中心
  • 发布日期:1989-06-15

Synthesis, spectrum and crystal structures of the chain unsymmetrical molybdenum-sulfur and tungsten-sulfur clusters [M3O2S8]^2^-

JIN GUOXIN;XIN XINQUAN;DAI ANBANG;WU JIANHUA;WANG BOYI;ZHENG PEIJU   

  • Published:1989-06-15

A2[M3O2S8](M = Mo, W; A = Bu4N, Ph4P, hexadecapyridinium, hexadecyltrimethylammonium) and (Et4N)2[W3O2S8] were prepared Both Bu4N complexes crystallize in space group P21/c. All complexes were characterized by elemental anal., IR and UV spectra. A mechanism for cluster formation is proposed.

Key words: CRYSTAL STRUCTURE DETERMINATION, INFRARED SPECTROPHOTOMETRY, MOLYBDENUM COMPLEX, CLUSTER COMPOUND, POLYNUCLEAR COMPLEX, SULFIDE COMPLEX, TUNGSTEN COMPLEX, ELECTRON TRANSFER REACTION

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