Investigation of single MoFe3S4 cubane-like cluster compounds IV: Synthesis and structure of novel doubly bridged single cubane-like cluster compound MoFe3S4(μ-Me2NCS2)4.2CH3CN

Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (11): 1075-1080. Next Articles

Original Articles

MoFe3S4单立方烷原子簇研究 IV:新型的双跨桥六配体单立方烷簇合物MoFe3S4(μ-Me2NCS2)2(Me2NCS2)4.2CH3CN的合成与结构

刘秋田;黄梁仁;杨瑜;卢嘉锡

中国科学院福建物质结构研究所

发布日期:1988-11-15

Investigation of single MoFe3S4 cubane-like cluster compounds IV: Synthesis and structure of novel doubly bridged single cubane-like cluster compound MoFe3S4(μ-Me2NCS2)4.2CH3CN

LIU QIUTIAN;HUANG LIANGREN;YANG YU;LU JIAXI

Published:1988-11-15

Abstract

MoFe3S4(Me2NCS2)5.CH2Cl2 and MoFe3S4(Me2NCS2)6.2CH2Cl2 (I), which were separated by fractional crystallization I is triclinic, space group P1, a 12.060(3), b 12.064(4), c 19.595(5), a 83.10(2), b 84.93(2), g 66.59(2)? Z = 2, for 5183 reflections R = 0.069. I is a novel cluster [MoFe3S4]6+ and contains 2 Me2NCS2 bridges. The structural features are reported and the observation that several single cubane-like cluster compounds containing various oxidation states can coexist in an assembly system is discussed.

Key words: MOLECULAR STRUCTURE, NITROGENASE, IRON COMPOUNDS, CLUSTER COMPOUND, CUBANE, BRIDGE COMPOUNDS, MOLYBDENUM COMPOUNDS, SULFUR COMPOUNDS, ACETONITRILE

CLC Number:

O611.662

Cite this article

LIU QIUTIAN;HUANG LIANGREN;YANG YU;LU JIAXI. Investigation of single MoFe3S4 cubane-like cluster compounds IV: Synthesis and structure of novel doubly bridged single cubane-like cluster compound MoFe3S4(μ-Me2NCS2)4.2CH3CN[J]. Acta Chimica Sinica, 1988, 46(11): 1075-1080.

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MoFe3S4单立方烷原子簇研究 IV:新型的双跨桥六配体单立方烷簇合物MoFe3S4(μ-Me2NCS2)2(Me2NCS2)4.2CH3CN的合成与结构

Investigation of single MoFe3S4 cubane-like cluster compounds IV: Synthesis and structure of novel doubly bridged single cubane-like cluster compound MoFe3S4(μ-Me2NCS2)4.2CH3CN

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