Frozen solution electron spin resonance study of some chromium(III) mixed ligand coordination compounds containing β-diketone

Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (3): 229-233. Previous Articles Next Articles

Original Articles

若干铬(III)含β-二酮混配配合物的冷冻态顺磁共振谱研究

陈克;戴胜

浙江大学化学系

发布日期:1988-03-15

Frozen solution electron spin resonance study of some chromium(III) mixed ligand coordination compounds containing β-diketone

CHEN KE;DAI SHENG

Published:1988-03-15

Abstract

By using frozen glassy state paramagnetic resonance, the ESR spectra of the Cr complex with b-diketones was studied. The trans and cis isomers and the cis-trans mixtures were investigated. The complexes studied were Cr(b-dik)Cl2Py2, where Py is pyridine, and b-dik are acetylacetone, benzoylacetone, dibenzoylmethane or oxalate radicals.

Key words: DATA HANDLING, PARAMAGNETIC RESONANCE, ENERGY LEVELS, ELECTRON SPIN RESONANCE, MATRICES, CHROMIUM COMPLEX, SPIN HAMILTONIAN PARAMETER, β-DIKETONES

CLC Number:

O641

Cite this article

CHEN KE;DAI SHENG. Frozen solution electron spin resonance study of some chromium(III) mixed ligand coordination compounds containing β-diketone[J]. Acta Chimica Sinica, 1988, 46(3): 229-233.

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若干铬(III)含β-二酮混配配合物的冷冻态顺磁共振谱研究

Frozen solution electron spin resonance study of some chromium(III) mixed ligand coordination compounds containing β-diketone

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