Reactivity of oxidative cleavage of 1,2-diketones mediated by selective binding of cyclodextrins and derivatives of amylose

Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (4): 402-404. Previous Articles Next Articles

Original Articles

环糊精和糖淀粉衍生物与1,2-二酮的选择结合及对其氧化断裂反应的调节作用

惠永正;盖永华;程贤恩

中国科学院上海有机化学研究所

发布日期:1988-04-15

Reactivity of oxidative cleavage of 1,2-diketones mediated by selective binding of cyclodextrins and derivatives of amylose

HUI YONGZHENG;GAI YONGHUA;CHENG XIANEN

Published:1988-04-15

Abstract

The effects of cyclodextrins and water soluble derivatives of amylose on the oxidative cleavage reaction of RCOCOR (R = Ph, p-tolyl) have been studied. In the case of cyclodextrins, it was found that the stability of inclusion complex depends on the fitness of cyclodextrins. However, when amylose was used as host, the stability of formed helical inclusion complex are determine by both of the degree of substitution of amylose derivative and hydrophobicity of the substrate.

Key words: CYCLODEXTRIN, DIKETONE, CRACKING REACTION, HYDROPHOBILITY, CLATHRATES, AMYLOSE, OXIDATION REACTION

CLC Number:

O621.16

Cite this article

HUI YONGZHENG;GAI YONGHUA;CHENG XIANEN. Reactivity of oxidative cleavage of 1,2-diketones mediated by selective binding of cyclodextrins and derivatives of amylose[J]. Acta Chimica Sinica, 1988, 46(4): 402-404.

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环糊精和糖淀粉衍生物与1,2-二酮的选择结合及对其氧化断裂反应的调节作用

Reactivity of oxidative cleavage of 1,2-diketones mediated by selective binding of cyclodextrins and derivatives of amylose

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