Studies on Nucleophilicity of \m-RS)(\m-XMgS)Fe2(CO)6: Synthesis and characterization of the Fe-S clusters (\m-RS)(\m-RS)[\m-Cp(CO)2FeS]Fe(CO)6

Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (12): 1188-1191. Previous Articles Next Articles

Original Articles

(μ-RS)(μ-XMgS)Fe2(CO)6亲核性能的研究:铁硫配合物(μ-RS)[μ-Cp(CO)2FeS]Fe2(CO)6

宋礼成;刘容刚;王积涛

南开大学化学系

发布日期:1987-12-15

Studies on Nucleophilicity of \m-RS)(\m-XMgS)Fe2(CO)6: Synthesis and characterization of the Fe-S clusters (\m-RS)(\m-RS)[\m-Cp(CO)2FeS]Fe(CO)6

SONG LICHENG;LIU RONGGANG;WANG JITAO

Published:1987-12-15

Abstract

The reaction of active Fe-S clusters (m-RS)(m-XMgS)Fe2(CO)6 (R = alkyl, Ph, PhCH2, PhCH2CH2, allyl, cycloalkyl; X = halo) with Cp(CO)2FeI gave a new class of Fe-S clusters containing the CpFe(CO)2 structural unit. Anal. of their 1H NMR spectra showed that each of the complexes exists only as one conformer. This conclusion has been confirmed by the single crystal structure anal. of the Me complex I.

Key words: CYCLOPENTADIENE P, IRON COMPLEX, CARBONYL COMPLEX, IODIDE, TETRAHYDROFURAN, CARBONYL COMPOUNDS, CHEMICAL BONDS, IRON COMPOUNDS, CLUSTER COMPOUND, NUCLEOPHILIC REACTION

CLC Number:

O627

Cite this article

SONG LICHENG;LIU RONGGANG;WANG JITAO. Studies on Nucleophilicity of \m-RS)(\m-XMgS)Fe2(CO)6: Synthesis and characterization of the Fe-S clusters (\m-RS)(\m-RS)[\m-Cp(CO)2FeS]Fe(CO)6[J]. Acta Chimica Sinica, 1987, 45(12): 1188-1191.

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(μ-RS)(μ-XMgS)Fe2(CO)6亲核性能的研究:铁硫配合物(μ-RS)[μ-Cp(CO)2FeS]Fe2(CO)6

Studies on Nucleophilicity of \m-RS)(\m-XMgS)Fe2(CO)6: Synthesis and characterization of the Fe-S clusters (\m-RS)(\m-RS)[\m-Cp(CO)2FeS]Fe(CO)6

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